Asset Details
Do you wish to reserve the book?
Nitrogen-doped carbon-based phenolic resin loaded with Pd NPs for hydrodechlorination of 4-Chlorophenol
Hey, we have placed the reservation for you!
By the way, why not check out events that you can attend while you pick your title.
Oops! Something went wrong.
Looks like we were not able to place the reservation. Kindly try again later.
Are you sure you want to remove the book from the shelf?
Nitrogen-doped carbon-based phenolic resin loaded with Pd NPs for hydrodechlorination of 4-Chlorophenol
Do you wish to request the book?
Nitrogen-doped carbon-based phenolic resin loaded with Pd NPs for hydrodechlorination of 4-Chlorophenol
Please be aware that the book you have requested cannot be checked out. If you would like to checkout this book, you can reserve another copy
We have requested the book for you!
Your request is successful and it will be processed during the Library working hours. Please check the status of your request in My Requests.
Oops! Something went wrong.
Looks like we were not able to place your request. Kindly try again later.
Journal Article
Nitrogen-doped carbon-based phenolic resin loaded with Pd NPs for hydrodechlorination of 4-Chlorophenol
2025
Overview
The catalytic hydrodechlorination (HDC) technology exhibits great flexibility and safety under mild conditions, and shows extremely promising application prospects for the degradation of 4-Chlorophenol (4-CP). Prepare the N-doped phenolic resin carbon support (PMF) using phenol, melamine and formaldehyde as raw materials, and load Pd nanoparticles (NPs) on it. The XPS results indicate that the Pd/PMF-800 has a higher Pyridine-N (24.8%) and a higher Pd
0
/(Pd
2+
+Pd
0
) ratio (65.4%). Moreover, the difference in electronegativity between the N atom and the resin carbon support enhances the binding energy between them. This enhancement promotes the nucleation of Pd NPs on the surface of the resin carbon support, thereby imparting higher stability to the Pd NPs. Due to these comprehensive advantages, Pd/PMF-800 has the highest dechlorination activity (k
obs
= 0.0594 min⁻¹) and stability (dechlorination rate is 91.56% after 5 cycle). Additionally, it also demonstrates efficient dehalogenation rates for 2-Chlorophenol and 4-Bromophenol. It can provide a catalyst that has high-efficiency dehalogenation performance, strong acid and alkali stability and adaptability, and can be recycled for the degradation of halogenated phenols in the environment.
Publisher
Nature Publishing Group UK,Nature Portfolio
