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Polyanion‐Type Electrode Materials for Sodium‐Ion Batteries
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Polyanion‐Type Electrode Materials for Sodium‐Ion Batteries
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Journal Article
Polyanion‐Type Electrode Materials for Sodium‐Ion Batteries
2017
Overview
Sodium‐ion batteries, representative members of the post‐lithium‐battery club, are very attractive and promising for large‐scale energy storage applications. The increasing technological improvements in sodium‐ion batteries (Na‐ion batteries) are being driven by the demand for Na‐based electrode materials that are resource‐abundant, cost‐effective, and long lasting. Polyanion‐type compounds are among the most promising electrode materials for Na‐ion batteries due to their stability, safety, and suitable operating voltages. The most representative polyanion‐type electrode materials are Na3V2(PO4)3 and NaTi2(PO4)3 for Na‐based cathode and anode materials, respectively. Both show superior electrochemical properties and attractive prospects in terms of their development and application in Na‐ion batteries. Carbonophosphate Na3MnCO3PO4 and amorphous FePO4 have also recently emerged and are contributing to further developing the research scope of polyanion‐type Na‐ion batteries. However, the typical low conductivity and relatively low capacity performance of such materials still restrict their development. This paper presents a brief review of the research progress of polyanion‐type electrode materials for Na‐ion batteries, summarizing recent accomplishments, highlighting emerging strategies, and discussing the remaining challenges of such systems.
Polyanion‐type electrode materials, combining the advantages of stability, safety and suitable operating voltages, are promising electrode candidates for sodium‐ion batteries aiming at large‐scale electrochemical energy storage. This article summarizes recent research into different types of these materials. The existing challenges and prospective strategies are also proposed and discussed.
Publisher
John Wiley & Sons, Inc,John Wiley and Sons Inc
