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Multiconfigurational nature of 5f orbitals in uranium and plutonium intermetallics

by Tobash, P.H , Allen, P.G , Sarrao, J.L , Bauer, E.D , Nordlund, D , Wang, D.L , Sokaras, D , Booth, C.H , Mitchell, J.N , Wall, M.A , Weng, T.-C , Torrez, M.A , Jiang, Yu

in absorption / Chemical compounds / Electrons / Emission spectroscopy / Fluorescence / Ground state / Intermetallics / Magnetism / Materials / Orbitals / Physical Sciences / Plutonium / Specific heat / spectroscopy / Spectrum analysis / Uranium / X-radiation

2012

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Multiconfigurational nature of 5f orbitals in uranium and plutonium intermetallics

by Tobash, P.H , Allen, P.G , Sarrao, J.L , Bauer, E.D , Nordlund, D , Wang, D.L , Sokaras, D , Booth, C.H , Mitchell, J.N , Wall, M.A , Weng, T.-C , Torrez, M.A , Jiang, Yu

2012

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Multiconfigurational nature of 5f orbitals in uranium and plutonium intermetallics

by Tobash, P.H , Allen, P.G , Sarrao, J.L , Bauer, E.D , Nordlund, D , Wang, D.L , Sokaras, D , Booth, C.H , Mitchell, J.N , Wall, M.A , Weng, T.-C , Torrez, M.A , Jiang, Yu

2012

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Journal Article

Multiconfigurational nature of 5f orbitals in uranium and plutonium intermetallics

Tobash, P.H,

Allen, P.G,

Sarrao, J.L,

Bauer, E.D,

Nordlund, D,

Wang, D.L,

Sokaras, D,

Booth, C.H,

Mitchell, J.N,

Wall, M.A,

Weng, T.-C,

Torrez, M.A,

Jiang, Yu

2012

Overview

Uranium and plutonium’s 5f electrons are tenuously poised between strongly bonding with ligand spd-states and residing close to the nucleus. The unusual properties of these elements and their compounds (e.g., the six different allotropes of elemental plutonium) are widely believed to depend on the related attributes of f-orbital occupancy and delocalization for which a quantitative measure is lacking. By employing resonant X-ray emission spectroscopy (RXES) and X-ray absorption near-edge structure (XANES) spectroscopy and making comparisons to specific heat measurements, we demonstrate the presence of multiconfigurational f-orbital states in the actinide elements U and Pu and in a wide range of uranium and plutonium intermetallic compounds. These results provide a robust experimental basis for a new framework toward understanding the strongly-correlated behavior of actinide materials.

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Publisher

National Academy of Sciences,National Acad Sciences

Subject

absorption

/ Chemical compounds

/ Electrons

/ Emission spectroscopy

/ Fluorescence

/ Ground state

/ Intermetallics