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Reconciling metal–silicate partitioning and late accretion in the Earth
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Reconciling metal–silicate partitioning and late accretion in the Earth
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Journal Article
Reconciling metal–silicate partitioning and late accretion in the Earth
2021
Overview
Highly siderophile elements (HSE), including platinum, provide powerful geochemical tools for studying planet formation. Late accretion of chondritic components to Earth after core formation has been invoked as the main source of mantle HSE. However, core formation could also have contributed to the mantle’s HSE content. Here we present measurements of platinum metal-silicate partitioning coefficients, obtained from laser-heated diamond anvil cell experiments, which demonstrate that platinum partitioning into metal is lower at high pressures and temperatures. Consequently, the mantle was likely enriched in platinum immediately following core-mantle differentiation. Core formation models that incorporate these results and simultaneously account for collateral geochemical constraints, lead to excess platinum in the mantle. A subsequent process such as iron exsolution or sulfide segregation is therefore required to remove excess platinum and to explain the mantle’s modern HSE signature. A vestige of this platinum-enriched mantle can potentially account for
186
Os-enriched ocean island basalt lavas.
Through platinum metal-silicate partitioning coefficient measurements, the authors here show that platinum partitioning into metal is lowered at high pressure–temperature conditions. This finding implies that the Earth’s mantle was likely enriched in platinum immediately following the core-mantle differentiation.
