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Valence band behaviour of zirconium oxide, Photoelectron and Auger spectroscopy study

by Steiner, Roland , Azdad, Zakaria , Moser, Lucas , Meyer, Ernst , Marot, Laurent

in 140/146 / 639/766/119/544 / 639/766/930/12 / Auger Spectra / Auger spectroscopy / Auger Transitions / Correct Charge / Electrons / Humanities and Social Sciences / multidisciplinary / Oxygen Incorporation / Photoelectron spectroscopy / Science / Science (multidisciplinary) / Spectroscopy / Spectrum analysis / Stoichiometry / Ultraviolet Photoelectron Spectroscopy / Zirconium

2018

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Valence band behaviour of zirconium oxide, Photoelectron and Auger spectroscopy study

by Steiner, Roland , Azdad, Zakaria , Moser, Lucas , Meyer, Ernst , Marot, Laurent

2018

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Valence band behaviour of zirconium oxide, Photoelectron and Auger spectroscopy study

by Steiner, Roland , Azdad, Zakaria , Moser, Lucas , Meyer, Ernst , Marot, Laurent

2018

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Journal Article

Valence band behaviour of zirconium oxide, Photoelectron and Auger spectroscopy study

Steiner, Roland,

Azdad, Zakaria,

Moser, Lucas,

Meyer, Ernst,

Marot, Laurent

2018

Overview

In this study X-ray Photoelectron Spectroscopy and Ultraviolet Photoelectron Spectroscopy were combined to investigate the effect of oxygen incorporation on the valence band behaviour of ZrO x . The Auger transitions involving valence bands are found to mimic the self-folded density of state measured using Ultraviolet Photoelectron Spectroscopy. The valence band once constructed in a sub-oxide form, stays at a fixed energy position despite the change in the stoichiometry. This behaviour is found to be useful in setting a reference for X-ray Photoelectron Spectroscopy charge correction. The results of the charged corrected spectra were compared to other methods and found to be in great agreement. Finally, a correlation between the core-level binding energy and the structural property of ZrO x is given.

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Nature Publishing Group UK,Nature Publishing Group,Nature Portfolio

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