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Lithium monoxide anion: A ground-state triplet with the strongest base to date
by
Tian, Zhixin
, Chan, Bun
, Kass, Steven R
, Radom, Leo
, Sullivan, Michael B
in
Acidity
/ Anions
/ Chemical bases
/ Chemical compounds
/ Electrons
/ Gases
/ Hydroxides
/ Ions
/ Lithium
/ Mass spectrometry
/ Mass spectroscopy
/ Methane
/ Physical Sciences
/ Protons
2008
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Lithium monoxide anion: A ground-state triplet with the strongest base to date
by
Tian, Zhixin
, Chan, Bun
, Kass, Steven R
, Radom, Leo
, Sullivan, Michael B
in
Acidity
/ Anions
/ Chemical bases
/ Chemical compounds
/ Electrons
/ Gases
/ Hydroxides
/ Ions
/ Lithium
/ Mass spectrometry
/ Mass spectroscopy
/ Methane
/ Physical Sciences
/ Protons
2008
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Do you wish to request the book?
Lithium monoxide anion: A ground-state triplet with the strongest base to date
by
Tian, Zhixin
, Chan, Bun
, Kass, Steven R
, Radom, Leo
, Sullivan, Michael B
in
Acidity
/ Anions
/ Chemical bases
/ Chemical compounds
/ Electrons
/ Gases
/ Hydroxides
/ Ions
/ Lithium
/ Mass spectrometry
/ Mass spectroscopy
/ Methane
/ Physical Sciences
/ Protons
2008
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Lithium monoxide anion: A ground-state triplet with the strongest base to date
Journal Article
Lithium monoxide anion: A ground-state triplet with the strongest base to date
2008
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Overview
Lithium monoxide anion (LiO⁻) has been generated in the gas phase and is found to be a stronger base than methyl anion (CH[Formula: see text]). This makes LiO⁻ the strongest base currently known, and it will be a challenge to produce a singly charged or multiply charged anion that is more basic. The experimental acidity of lithium hydroxide is ΔH°[Formula: see text] = 425.7 ± 6.1 kcal·mol⁻¹ (1 kcal = 4.184 kJ) and, when combined with results of high-level computations, leads to our best estimate for the acidity of 426 ± 2 kcal·mol⁻¹.
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