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Visible-Light Photocatalytic Reduction of Aryl Halides as a Source of Aryl Radicals
by
Lu, Xiaoyan
, Hu, Menghui
, Chen, Rongxiang
, Lan, Jihong
, Duo, Fangfang
in
Aromatic compounds
/ aryl halides
/ aryl radicals
/ Chloride
/ Electron transport
/ Energy
/ Fluorides
/ Halides
/ Hydrogenation
/ Ligands
/ Light
/ Photocatalysis
/ photoinduced electron transfer
/ reduction
/ Review
/ Semiconductors
/ visible light
2022
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Visible-Light Photocatalytic Reduction of Aryl Halides as a Source of Aryl Radicals
by
Lu, Xiaoyan
, Hu, Menghui
, Chen, Rongxiang
, Lan, Jihong
, Duo, Fangfang
in
Aromatic compounds
/ aryl halides
/ aryl radicals
/ Chloride
/ Electron transport
/ Energy
/ Fluorides
/ Halides
/ Hydrogenation
/ Ligands
/ Light
/ Photocatalysis
/ photoinduced electron transfer
/ reduction
/ Review
/ Semiconductors
/ visible light
2022
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Do you wish to request the book?
Visible-Light Photocatalytic Reduction of Aryl Halides as a Source of Aryl Radicals
by
Lu, Xiaoyan
, Hu, Menghui
, Chen, Rongxiang
, Lan, Jihong
, Duo, Fangfang
in
Aromatic compounds
/ aryl halides
/ aryl radicals
/ Chloride
/ Electron transport
/ Energy
/ Fluorides
/ Halides
/ Hydrogenation
/ Ligands
/ Light
/ Photocatalysis
/ photoinduced electron transfer
/ reduction
/ Review
/ Semiconductors
/ visible light
2022
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Visible-Light Photocatalytic Reduction of Aryl Halides as a Source of Aryl Radicals
Journal Article
Visible-Light Photocatalytic Reduction of Aryl Halides as a Source of Aryl Radicals
2022
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Overview
Aryl- and heteroaryl units are present in a wide variety of natural products, pharmaceuticals, and functional materials. The method for reduction of aryl halides with ubiquitous distribution is highly sought after for late-stage construction of various aromatic compounds. The visible-light-driven reduction of aryl halides to aryl radicals by electron transfer provides an efficient, simple, and environmentally friendly method for the construction of aromatic compounds. This review summarizes the recent progress in the generation of aryl radicals by visible-light-driven reduction of aryl halides with metal complexes, organic compounds, semiconductors as catalysts, and alkali-assisted reaction system. The ability and mechanism of reduction of aromatic halides in various visible light induced systems are summarized, intending to illustrate a comprehensive introduction of this research topic to the readers.
Publisher
MDPI AG,MDPI
Subject
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