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Bottom-up growth of homogeneous Moiré superlattices in bismuth oxychloride spiral nanosheets
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Bottom-up growth of homogeneous Moiré superlattices in bismuth oxychloride spiral nanosheets
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Journal Article
Bottom-up growth of homogeneous Moiré superlattices in bismuth oxychloride spiral nanosheets
2019
Overview
Moiré superlattices (MSLs) are modulated structures produced from homogeneous or heterogeneous 2D layers stacked with a twist angle and/or lattice mismatch. Expanding the range of available materials, methods for fabricating MSL, and realization of unique emergent properties are key challenges. Here we report a facile bottom-up synthesis of homogeneous MSL based on a wide-gap 2D semiconductor, BiOCl, using a one-pot solvothermal approach with robust reproducibility. Unlike previous MSLs usually prepared by directly stacking two monolayers, our BiOCl MSLs are realized in a scalable, direct way through chemical growth of spiral-type nanosheets driven by screw-dislocations. We find emergent properties including large band gap reduction (∼0.6 eV), two-fold increase in carrier lifetime, and strongly enhanced photocatalytic activity. First-principles calculations reveal that such unusual properties can be ascribed to the locally enhanced inter-layer coupling associated with the Moiré potential modulation. Our results demonstrate the promise of MSL materials for chemical and physical functions.
Expanding the range of available materials, methods for fabricating Moiré superlattices, and realization of new emergent properties are key challenges. Here the authors report a facile bottom-up synthesis of homogeneous Moiré superlattices based on a wide-gap 2D semiconductor, bismuth oxychloride.
Publisher
Nature Publishing Group UK,Nature Publishing Group,Nature Portfolio
Subject
