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LC-high resolution MS in environmental analysis: from target screening to the identification of unknowns
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LC-high resolution MS in environmental analysis: from target screening to the identification of unknowns
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Journal Article
LC-high resolution MS in environmental analysis: from target screening to the identification of unknowns
2010
Overview
This article provides an overview of the state-of-the-art and future trends of the application of LC-high resolution mass spectrometry to the environmental analysis of polar micropollutants. Highly resolved and accurate hybrid tandem mass spectrometry such as quadrupole/time-of-flight and linear ion trap/orbitrap technology allows for a more reliable target analysis with reference standards, a screening for suspected analytes without reference standards, and a screening for unknowns. A reliable identification requires both high resolving power and high mass spectral accuracy to increase selectivity against the matrix background and for a correct molecular formula assignment to unknown compounds. For the identification and structure elucidation of unknown compounds within a reasonable time frame and with a reasonable soundness, advanced automated software solutions as well as improved prediction systems for theoretical fragmentation patterns, retention times, and ionization behavior are needed. [graphic removed]
Publisher
Berlin/Heidelberg : Springer-Verlag,Springer-Verlag,Springer,Springer Nature B.V
Subject
/ Analysis
/ Characterization and Evaluation of Materials
/ Chemistry and Materials Science
/ Chromatographic methods and physical methods associated with chromatography
/ Exact sciences and technology
/ Global environmental pollution
/ High resolution mass spectrometry
/ High resolution spectroscopy
/ Identification and classification
/ Methods
/ Monitoring/Environmental Analysis
/ Other chromatographic methods
/ Spectrometric and optical methods
/ Trends
