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Self-sustainable protonic ceramic electrochemical cells using a triple conducting electrode for hydrogen and power production
by
Zhang, Yunya
, Orme, Christopher J.
, Jiang, Chao
, Ding, Hanping
, Wu, Wei
, Ding, Yong
, Ding, Dong
, Bian, Wenjuan
, Wang, Lucun
, Singh, Prabhakar
, Hu, Boxun
in
08 - HYDROGEN
/ 140/146
/ 140/58
/ 147/135
/ 147/143
/ 639/301/299/161/893
/ 639/4077/909/4086
/ 639/638/263/915
/ 639/925/357/354
/ Chemical reduction
/ Conduction
/ Conductors
/ Electric power generation
/ Electricity
/ Electrochemical analysis
/ Electrochemical cells
/ Electrochemistry
/ Electrodes
/ Electrolysis
/ Electrolytic cells
/ Fuel cells
/ Humanities and Social Sciences
/ Hydrogen
/ Hydrogen permeation
/ hydrogen production, electrochemical cell, proton conduction
/ multidisciplinary
/ Oxidation
/ Oxygen
/ Oxygen reduction reactions
/ Perovskites
/ Proton conduction
/ Renewable fuels
/ Science
/ Science (multidisciplinary)
/ Sustainability
/ Sustainable energy
2020
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Self-sustainable protonic ceramic electrochemical cells using a triple conducting electrode for hydrogen and power production
by
Zhang, Yunya
, Orme, Christopher J.
, Jiang, Chao
, Ding, Hanping
, Wu, Wei
, Ding, Yong
, Ding, Dong
, Bian, Wenjuan
, Wang, Lucun
, Singh, Prabhakar
, Hu, Boxun
in
08 - HYDROGEN
/ 140/146
/ 140/58
/ 147/135
/ 147/143
/ 639/301/299/161/893
/ 639/4077/909/4086
/ 639/638/263/915
/ 639/925/357/354
/ Chemical reduction
/ Conduction
/ Conductors
/ Electric power generation
/ Electricity
/ Electrochemical analysis
/ Electrochemical cells
/ Electrochemistry
/ Electrodes
/ Electrolysis
/ Electrolytic cells
/ Fuel cells
/ Humanities and Social Sciences
/ Hydrogen
/ Hydrogen permeation
/ hydrogen production, electrochemical cell, proton conduction
/ multidisciplinary
/ Oxidation
/ Oxygen
/ Oxygen reduction reactions
/ Perovskites
/ Proton conduction
/ Renewable fuels
/ Science
/ Science (multidisciplinary)
/ Sustainability
/ Sustainable energy
2020
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Self-sustainable protonic ceramic electrochemical cells using a triple conducting electrode for hydrogen and power production
by
Zhang, Yunya
, Orme, Christopher J.
, Jiang, Chao
, Ding, Hanping
, Wu, Wei
, Ding, Yong
, Ding, Dong
, Bian, Wenjuan
, Wang, Lucun
, Singh, Prabhakar
, Hu, Boxun
in
08 - HYDROGEN
/ 140/146
/ 140/58
/ 147/135
/ 147/143
/ 639/301/299/161/893
/ 639/4077/909/4086
/ 639/638/263/915
/ 639/925/357/354
/ Chemical reduction
/ Conduction
/ Conductors
/ Electric power generation
/ Electricity
/ Electrochemical analysis
/ Electrochemical cells
/ Electrochemistry
/ Electrodes
/ Electrolysis
/ Electrolytic cells
/ Fuel cells
/ Humanities and Social Sciences
/ Hydrogen
/ Hydrogen permeation
/ hydrogen production, electrochemical cell, proton conduction
/ multidisciplinary
/ Oxidation
/ Oxygen
/ Oxygen reduction reactions
/ Perovskites
/ Proton conduction
/ Renewable fuels
/ Science
/ Science (multidisciplinary)
/ Sustainability
/ Sustainable energy
2020
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Self-sustainable protonic ceramic electrochemical cells using a triple conducting electrode for hydrogen and power production
Journal Article
Self-sustainable protonic ceramic electrochemical cells using a triple conducting electrode for hydrogen and power production
2020
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Overview
The protonic ceramic electrochemical cell (PCEC) is an emerging and attractive technology that converts energy between power and hydrogen using solid oxide proton conductors at intermediate temperatures. To achieve efficient electrochemical hydrogen and power production with stable operation, highly robust and durable electrodes are urgently desired to facilitate water oxidation and oxygen reduction reactions, which are the critical steps for both electrolysis and fuel cell operation, especially at reduced temperatures. In this study, a triple conducting oxide of PrNi
0.5
Co
0.5
O
3-δ
perovskite is developed as an oxygen electrode, presenting superior electrochemical performance at 400~600 °C. More importantly, the self-sustainable and reversible operation is successfully demonstrated by converting the generated hydrogen in electrolysis mode to electricity without any hydrogen addition. The excellent electrocatalytic activity is attributed to the considerable proton conduction, as confirmed by hydrogen permeation experiment, remarkable hydration behavior and computations.
While producing renewable fuel is crucial for a sustainable energy economy, there is still a need for active and durable materials capable of efficient fuel generation and utilization. Here, authors demonstrate a triple-conductive oxide as an oxygen electrode for H
2
or electricity production.
Publisher
Nature Publishing Group UK,Nature Publishing Group,Nature Portfolio
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