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Correlation between manganese dissolution and dynamic phase stability in spinel-based lithium-ion battery
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Correlation between manganese dissolution and dynamic phase stability in spinel-based lithium-ion battery
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Journal Article
Correlation between manganese dissolution and dynamic phase stability in spinel-based lithium-ion battery
2019
Overview
Historically long accepted to be the singular root cause of capacity fading, transition metal dissolution has been reported to severely degrade the anode. However, its impact on the cathode behavior remains poorly understood. Here we show the correlation between capacity fading and phase/surface stability of an LiMn
2
O
4
cathode. It is revealed that a combination of structural transformation and transition metal dissolution dominates the cathode capacity fading. LiMn
2
O
4
exhibits irreversible phase transitions driven by manganese(III) disproportionation and Jahn-Teller distortion, which in conjunction with particle cracks results in serious manganese dissolution. Meanwhile, fast manganese dissolution in turn triggers irreversible structural evolution, and as such, forms a detrimental cycle constantly consuming active cathode components. Furthermore, lithium-rich LiMn
2
O
4
with lithium/manganese disorder and surface reconstruction could effectively suppress the irreversible phase transition and manganese dissolution. These findings close the loop of understanding capacity fading mechanisms and allow for development of longer life batteries.
To unlock the potential of Mn-based cathode materials, the fast capacity fading process has to be first understood. Here the authors utilize advanced characterization techniques to look at a spinel LiMn
2
O
4
system, revealing that a combination of irreversible structural transformations and Mn dissolution takes responsibility.
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