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A late-transition metal oxo complex: K7Na9O=PtIV(H2O)L2, L = PW9O349
by
Piccoli, Paula M B
, Cao, Rui
, Schultz, Arthur J
, Neiwert, Wade A
, Musaev, Djamaladdin G
, Anderson, Travis M
, Kirk, Martin L
, Koetzle, Thomas F
, Morokuma, Keiji
, Hill, Craig L
in
Chemical Phenomena
/ Chemistry, Physical
/ Crystallization
/ Crystallography, X-Ray
/ Electrons
/ Fourier Analysis
/ Hydrogen-Ion Concentration
/ Ligands
/ Molecular Structure
/ Neutron Diffraction
/ Oxidation-Reduction
/ Oxygen - chemistry
/ Platinum - chemistry
/ Platinum Compounds - chemical synthesis
/ Platinum Compounds - chemistry
/ Platinum Compounds - isolation & purification
/ Spectrum Analysis
/ Temperature
/ Tungsten - chemistry
/ Tungsten Compounds - chemical synthesis
/ Tungsten Compounds - chemistry
/ Tungsten Compounds - isolation & purification
2004
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A late-transition metal oxo complex: K7Na9O=PtIV(H2O)L2, L = PW9O349
by
Piccoli, Paula M B
, Cao, Rui
, Schultz, Arthur J
, Neiwert, Wade A
, Musaev, Djamaladdin G
, Anderson, Travis M
, Kirk, Martin L
, Koetzle, Thomas F
, Morokuma, Keiji
, Hill, Craig L
in
Chemical Phenomena
/ Chemistry, Physical
/ Crystallization
/ Crystallography, X-Ray
/ Electrons
/ Fourier Analysis
/ Hydrogen-Ion Concentration
/ Ligands
/ Molecular Structure
/ Neutron Diffraction
/ Oxidation-Reduction
/ Oxygen - chemistry
/ Platinum - chemistry
/ Platinum Compounds - chemical synthesis
/ Platinum Compounds - chemistry
/ Platinum Compounds - isolation & purification
/ Spectrum Analysis
/ Temperature
/ Tungsten - chemistry
/ Tungsten Compounds - chemical synthesis
/ Tungsten Compounds - chemistry
/ Tungsten Compounds - isolation & purification
2004
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![A late-transition metal oxo complex: K7Na9O=PtIV(H2O)L2, L = PW9O349](https://www.mbrl.ae/o/mbrl-theme/images/site-assets/generic/no-book-image.png)
A late-transition metal oxo complex: K7Na9O=PtIV(H2O)L2, L = PW9O349
by
Piccoli, Paula M B
, Cao, Rui
, Schultz, Arthur J
, Neiwert, Wade A
, Musaev, Djamaladdin G
, Anderson, Travis M
, Kirk, Martin L
, Koetzle, Thomas F
, Morokuma, Keiji
, Hill, Craig L
in
Chemical Phenomena
/ Chemistry, Physical
/ Crystallization
/ Crystallography, X-Ray
/ Electrons
/ Fourier Analysis
/ Hydrogen-Ion Concentration
/ Ligands
/ Molecular Structure
/ Neutron Diffraction
/ Oxidation-Reduction
/ Oxygen - chemistry
/ Platinum - chemistry
/ Platinum Compounds - chemical synthesis
/ Platinum Compounds - chemistry
/ Platinum Compounds - isolation & purification
/ Spectrum Analysis
/ Temperature
/ Tungsten - chemistry
/ Tungsten Compounds - chemical synthesis
/ Tungsten Compounds - chemistry
/ Tungsten Compounds - isolation & purification
2004
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A late-transition metal oxo complex: K7Na9O=PtIV(H2O)L2, L = PW9O349
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Journal Article
A late-transition metal oxo complex: K7Na9O=PtIV(H2O)L2, L = PW9O349
2004
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Overview
Terminal mono-oxo complexes of the late transition metal elements have long been considered too unstable to synthesize because of repulsion between the oxygen electrons and the mostly filled metal d orbitals. A platinum(IV)-oxo compound flanked by two polytungstate ligands, K7Na9[O=Pt(H2O)L2], L = [PW9O34(9-)], has now been prepared and isolated at room temperature as air-stable brown crystals. X-ray and neutron diffraction at 30 kelvin revealed a very short [1.720(18) angstrom] Pt-O bond and no evidence of a hydrogen atom at the terminal oxygen, ruling out a better precedented Pt-OH complex. Density functional theory and spectroscopic data account for the stability of the Pt(IV)-oxo unit by electron withdrawal into delocalized orbitals of the polytungstates.
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