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Design and Synthesis of Novel Cage like CuFe.sub.2O.sub.4 Hollow Nanostructure as an Efficient Catalyst for Synthesis of 4,4
by
Khalifeh, Reza
, Shahimoridi, Roghayeh
, Rajabzadeh, Maryam
in
Copper
/ Hydrazine
2019
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Design and Synthesis of Novel Cage like CuFe.sub.2O.sub.4 Hollow Nanostructure as an Efficient Catalyst for Synthesis of 4,4
by
Khalifeh, Reza
, Shahimoridi, Roghayeh
, Rajabzadeh, Maryam
in
Copper
/ Hydrazine
2019
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Design and Synthesis of Novel Cage like CuFe.sub.2O.sub.4 Hollow Nanostructure as an Efficient Catalyst for Synthesis of 4,4
Journal Article
Design and Synthesis of Novel Cage like CuFe.sub.2O.sub.4 Hollow Nanostructure as an Efficient Catalyst for Synthesis of 4,4
2019
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Overview
Cage like CuFe.sub.2O.sub.4 hollow nanostructure has been synthesized successfully using hard template method under the hydrothermal condition. Cu(NO.sub.3).sub.2·6H.sub.2O, Fe(NO.sub.3).sub.2·9H.sub.2O and glucose were dissolved in water, and the mixture was heated to 180 °C in an autoclave. The removal of carbon was achieved by calcination at 800 °C and finally, the cage like CuFe.sub.2O.sub.4 hollow structure was obtained. This cage like CuFe.sub.2O.sub.4 hollow structure was characterized by FE-SEM, EDS, TEM and XRD. The catalytic performance of this hollow nanostructure was evaluated for the synthesis of bis pyrazol-5-ols. To this end, the one pot condensation reactions of phenylhydrazine, ethyl acetoacetate and different aromatic aldehyde at 80 °C under the solvent free condition were performed. The optimum amount of applied catalyst for this transformation was obtained to be 0.04 mol %. Noteworthy, catalyst was easily recoverable and was reused for 7 times with the remaining of its initial structure as well as its catalytic activity.
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