Asset Details
Do you wish to reserve the book?
A Pair of Multifunctional Cu Enantiomers with Zero–Field Single–Molecule Magnet Behaviors, Proton Conduction Properties and Magneto–Optical Faraday Effects
Hey, we have placed the reservation for you!
By the way, why not check out events that you can attend while you pick your title.
Oops! Something went wrong.
Looks like we were not able to place the reservation. Kindly try again later.
Are you sure you want to remove the book from the shelf?
A Pair of Multifunctional Cu Enantiomers with Zero–Field Single–Molecule Magnet Behaviors, Proton Conduction Properties and Magneto–Optical Faraday Effects
Do you wish to request the book?
A Pair of Multifunctional Cu Enantiomers with Zero–Field Single–Molecule Magnet Behaviors, Proton Conduction Properties and Magneto–Optical Faraday Effects
Please be aware that the book you have requested cannot be checked out. If you would like to checkout this book, you can reserve another copy
We have requested the book for you!
Your request is successful and it will be processed during the Library working hours. Please check the status of your request in My Requests.
Oops! Something went wrong.
Looks like we were not able to place your request. Kindly try again later.
Journal Article
A Pair of Multifunctional Cu Enantiomers with Zero–Field Single–Molecule Magnet Behaviors, Proton Conduction Properties and Magneto–Optical Faraday Effects
2023
Overview
Multifunctional materials with a coexistence of proton conduction properties, single–molecule magnet (SMM) behaviors and magneto–optical Faraday effects have rarely been reported. Herein, a new pair of Cu(II)–Dy(III) enantiomers, [DyCu[sub.2](RR/SS–H[sub.2]L)[sub.2](H[sub.2]O)[sub.4](NO[sub.3])[sub.2]]·(NO[sub.3])·(H[sub.2]O) (R–1 and S–1) (H[sub.4]L = [RR/SS] –N,N′–bis [3–hydroxysalicylidene] –1,2–cyclohexanediamine), has been designed and prepared using homochiral Schiff–base ligands. R–1 and S–1 contain linear Cu(II)–Dy(III)–Cu(II) trinuclear units and possess 1D stacking channels within their supramolecular networks. R–1 and S–1 display chiral optical activity and strong magneto–optical Faraday effects. Moreover, R–1 shows a zero–field SMM behavior. In addition, R–1 demonstrates humidity– and temperature–dependent proton conductivity with optimal values of 1.34 × 10[sup.−4] S·cm[sup.−1] under 50 °C and 98% relative humidity (RH), which is related to a 1D extended H–bonded chain constructed by water molecules, nitrate and phenol groups of the RR–H[sub.2]L ligand.
Publisher
MDPI AG
Subject
