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Self-assembled guanine ribbons as wide-bandgap semiconductors
by
Calzolari, A
, Molinari, E
, R Di Felice
, Garbesi, a
in
Conduction bands
/ Dipoles
/ First principles
/ Hydrogen bonding
/ Nanotechnology devices
/ Self-assembly
/ Semiconductors
/ Wide bandgap semiconductors
2001
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Self-assembled guanine ribbons as wide-bandgap semiconductors
by
Calzolari, A
, Molinari, E
, R Di Felice
, Garbesi, a
in
Conduction bands
/ Dipoles
/ First principles
/ Hydrogen bonding
/ Nanotechnology devices
/ Self-assembly
/ Semiconductors
/ Wide bandgap semiconductors
2001
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Self-assembled guanine ribbons as wide-bandgap semiconductors
Paper
Self-assembled guanine ribbons as wide-bandgap semiconductors
2001
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Overview
We present a first principle study about the stability and the electronic properties of a new biomolecular solid-state material, obtained by the self-assembling of guanine (G) molecules. We consider hydrogen-bonded planar ribbons in isolated and stacked configurations. These aggregates present electronic properties similar to inorganic wide-bandgap semiconductors. The formation of Bloch-type orbitals is observed along the stacking direction, while it is negligible in the ribbon plane. Global band-like conduction may be affected by a dipole-field which spontaneously arises along the ribbon axis. Our results indicate that G-ribbon assemblies are promising materials for biomolecular nanodevices, consistently with recent experimental results.
Publisher
Cornell University Library, arXiv.org
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