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Derivatization of Lignin via Ternary Eutectic Solvent Systems for Enhanced Functionalities Hydrogel
by
Qin, Tianci
, Zhang, Zhili
, Yin, Xiuxin
, Li, Fengfeng
in
Acids
/ Adsorptivity
/ Agricultural practices
/ Biopolymers
/ Chloride
/ Contaminants
/ Crosslinking
/ Fourier transforms
/ Hemodialysis
/ Hydrogels
/ Hydrogen bonds
/ Kinetics
/ Lignin
/ Molecular weight
/ Soil remediation
/ Soil resistance
/ Solvents
/ Sustainable materials
/ Swelling ratio
/ Water absorption
2025
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Derivatization of Lignin via Ternary Eutectic Solvent Systems for Enhanced Functionalities Hydrogel
by
Qin, Tianci
, Zhang, Zhili
, Yin, Xiuxin
, Li, Fengfeng
in
Acids
/ Adsorptivity
/ Agricultural practices
/ Biopolymers
/ Chloride
/ Contaminants
/ Crosslinking
/ Fourier transforms
/ Hemodialysis
/ Hydrogels
/ Hydrogen bonds
/ Kinetics
/ Lignin
/ Molecular weight
/ Soil remediation
/ Soil resistance
/ Solvents
/ Sustainable materials
/ Swelling ratio
/ Water absorption
2025
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Derivatization of Lignin via Ternary Eutectic Solvent Systems for Enhanced Functionalities Hydrogel
by
Qin, Tianci
, Zhang, Zhili
, Yin, Xiuxin
, Li, Fengfeng
in
Acids
/ Adsorptivity
/ Agricultural practices
/ Biopolymers
/ Chloride
/ Contaminants
/ Crosslinking
/ Fourier transforms
/ Hemodialysis
/ Hydrogels
/ Hydrogen bonds
/ Kinetics
/ Lignin
/ Molecular weight
/ Soil remediation
/ Soil resistance
/ Solvents
/ Sustainable materials
/ Swelling ratio
/ Water absorption
2025
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Derivatization of Lignin via Ternary Eutectic Solvent Systems for Enhanced Functionalities Hydrogel
Journal Article
Derivatization of Lignin via Ternary Eutectic Solvent Systems for Enhanced Functionalities Hydrogel
2025
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Overview
This study presents a novel structural modification strategy for lignin, utilizing a ternary eutectic solvent system (TESS), which induces targeted derivatization. The resulting lignin-based functional hydrogel (LBFH), prepared via rational cross-linking of derivatized lignin precursors, exhibits exceptional hygroscopic properties, with a water swelling ratio of 934.0%. Water absorption kinetics were subjected to rigorous analysis through the employment of a dual-modeling strategy that incorporates Schott kinetics and Fickian diffusion mechanisms, thereby elucidating the synergistic dynamic processes underlying surface adsorption and matrix penetration. Remarkably, LBFH maintains 48.6% water retention capacity after 7 days atmospheric exposure (25 °C, 60% RH), demonstrating unprecedented environmental stability among biopolymer hydrogels. The engineered properties of LBFH suggest its potential application in sustainable agricultural practices as drought-resistant soil amendments, and in environmental remediation as contaminant-adsorptive matrices.
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