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Derivatization of Lignin via Ternary Eutectic Solvent Systems for Enhanced Functionalities Hydrogel
Derivatization of Lignin via Ternary Eutectic Solvent Systems for Enhanced Functionalities Hydrogel
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Derivatization of Lignin via Ternary Eutectic Solvent Systems for Enhanced Functionalities Hydrogel
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Derivatization of Lignin via Ternary Eutectic Solvent Systems for Enhanced Functionalities Hydrogel
Derivatization of Lignin via Ternary Eutectic Solvent Systems for Enhanced Functionalities Hydrogel

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Derivatization of Lignin via Ternary Eutectic Solvent Systems for Enhanced Functionalities Hydrogel
Derivatization of Lignin via Ternary Eutectic Solvent Systems for Enhanced Functionalities Hydrogel
Journal Article

Derivatization of Lignin via Ternary Eutectic Solvent Systems for Enhanced Functionalities Hydrogel

2025
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Overview
This study presents a novel structural modification strategy for lignin, utilizing a ternary eutectic solvent system (TESS), which induces targeted derivatization. The resulting lignin-based functional hydrogel (LBFH), prepared via rational cross-linking of derivatized lignin precursors, exhibits exceptional hygroscopic properties, with a water swelling ratio of 934.0%. Water absorption kinetics were subjected to rigorous analysis through the employment of a dual-modeling strategy that incorporates Schott kinetics and Fickian diffusion mechanisms, thereby elucidating the synergistic dynamic processes underlying surface adsorption and matrix penetration. Remarkably, LBFH maintains 48.6% water retention capacity after 7 days atmospheric exposure (25 °C, 60% RH), demonstrating unprecedented environmental stability among biopolymer hydrogels. The engineered properties of LBFH suggest its potential application in sustainable agricultural practices as drought-resistant soil amendments, and in environmental remediation as contaminant-adsorptive matrices.