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High-Gradient Magnetic Separation of Compact Fluorescent Lamp Phosphors: Elucidation of the Removal Dynamics in a Rotary Permanent Magnet Separator
by
Eckert, Kerstin
, Lei, Zhe
, Rudolph, Martin
, Franzreb, Matthias
, Drobot, Björn
, Li, Zichao
, Lederer, Franziska
, Boelens, Peter
in
Analytical methods
/ Backwash
/ Dynamics
/ End of life
/ Factor analysis
/ Fluorescence
/ Fluorescence spectroscopy
/ Fluorescent lamps
/ Fluorescent lighting
/ Investigations
/ Lamps
/ Laser induced fluorescence
/ Lasers
/ Magnetic fields
/ Magnetic separation
/ Magnetic separators
/ Marine molluscs
/ Peptides
/ Permanent magnets
/ Phosphors
/ Physical properties
/ Rare earth elements
/ Raw materials
/ Removal
/ Separation
/ Separation processes
/ Separators
/ Spectroscopy
/ Water flow
2021
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High-Gradient Magnetic Separation of Compact Fluorescent Lamp Phosphors: Elucidation of the Removal Dynamics in a Rotary Permanent Magnet Separator
by
Eckert, Kerstin
, Lei, Zhe
, Rudolph, Martin
, Franzreb, Matthias
, Drobot, Björn
, Li, Zichao
, Lederer, Franziska
, Boelens, Peter
in
Analytical methods
/ Backwash
/ Dynamics
/ End of life
/ Factor analysis
/ Fluorescence
/ Fluorescence spectroscopy
/ Fluorescent lamps
/ Fluorescent lighting
/ Investigations
/ Lamps
/ Laser induced fluorescence
/ Lasers
/ Magnetic fields
/ Magnetic separation
/ Magnetic separators
/ Marine molluscs
/ Peptides
/ Permanent magnets
/ Phosphors
/ Physical properties
/ Rare earth elements
/ Raw materials
/ Removal
/ Separation
/ Separation processes
/ Separators
/ Spectroscopy
/ Water flow
2021
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High-Gradient Magnetic Separation of Compact Fluorescent Lamp Phosphors: Elucidation of the Removal Dynamics in a Rotary Permanent Magnet Separator
by
Eckert, Kerstin
, Lei, Zhe
, Rudolph, Martin
, Franzreb, Matthias
, Drobot, Björn
, Li, Zichao
, Lederer, Franziska
, Boelens, Peter
in
Analytical methods
/ Backwash
/ Dynamics
/ End of life
/ Factor analysis
/ Fluorescence
/ Fluorescence spectroscopy
/ Fluorescent lamps
/ Fluorescent lighting
/ Investigations
/ Lamps
/ Laser induced fluorescence
/ Lasers
/ Magnetic fields
/ Magnetic separation
/ Magnetic separators
/ Marine molluscs
/ Peptides
/ Permanent magnets
/ Phosphors
/ Physical properties
/ Rare earth elements
/ Raw materials
/ Removal
/ Separation
/ Separation processes
/ Separators
/ Spectroscopy
/ Water flow
2021
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High-Gradient Magnetic Separation of Compact Fluorescent Lamp Phosphors: Elucidation of the Removal Dynamics in a Rotary Permanent Magnet Separator
Journal Article
High-Gradient Magnetic Separation of Compact Fluorescent Lamp Phosphors: Elucidation of the Removal Dynamics in a Rotary Permanent Magnet Separator
2021
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Overview
In an ongoing effort towards a more sustainable rare-earth element market, there is a high potential for an efficient recycling of rare-earth elements from end-of-life compact fluorescent lamps by physical separation of the individual phosphors. In this study, we investigate the separation of five fluorescent lamp particles by high-gradient magnetic separation in a rotary permanent magnet separator. We thoroughly characterize the phosphors by ICP-MS, laser diffraction analysis, gas displacement pycnometry, surface area analysis, SQUID-VSM, and Time-Resolved Laser-Induced Fluorescence Spectroscopy. We present a fast and reliable quantification method for mixtures of the investigated phosphors, based on a combination of Time-Resolved Laser-Induced Fluorescence Spectroscopy and parallel factor analysis. With this method, we were able to monitor each phosphors’ removal dynamics in the high-gradient magnetic separator and we estimate that the particles’ removal efficiencies are proportional to (d2·χ)1/3. Finally, we have found that the removed phosphors can readily be recovered easily from the separation cell by backwashing with an intermittent air–water flow. This work should contribute to a better understanding of the phosphors’ separability by high-gradient magnetic separation and can simultaneously be considered to be an important preparation for an upscalable separation process with (bio)functionalized superparamagnetic carriers.
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