Journal Article

Improving the intrinsic electronic conductivity of NiMoO4 anodes by phosphorous doping for high lithium storage

Yue, Luchao, Ma, Chaoqun, Wu, Zhenguo, Luo, Yonglan, Sun, Xuping, Alshehri, Abdulmohsen Ali, Liu, Yang, Zhong, Benhe, Yan, Shihai, Zhang, Fang, Zhao, Wenxi, Liu, Qian, Guo, Xiaodong, Alzahrani, Khalid Ahmed

2022

Overview

Heteroatom doping is one of the most promising strategies toward regulating intrinsically sluggish electronic conductivity and kinetic reaction of transition metal oxides for enhancing their lithium storage. Herein, we designed phosphorus-doped NiMoO 4 nanorods (P-NiMoO 4 ) by using a facile hydrothermal method and subsequent low-temperature phosphorization treatment. Phosphorus doping played an indispensable role in significantly improving electronic conductivity and the Li + diffusion kinetics of NiMoO 4 materials. Experimental investigation and density functional theory calculation demonstrated that phosphorus doping can expand the interplanar spacing and alter electronic structures of NiMoO 4 nanorods. Meanwhile, the introduced phosphorus dopant can generate some oxygen vacancies on the surface of NiMoO 4 , which can accelerate Li + diffusion kinetics and provide more active site for lithium storage. As excepted, P-NiMoO 4 electrode delivered a high specific capacity (1,130 mAh·g −1 at 100 mA·g −1 after 100 cycles), outstanding cycling durability (945 mAh·g −1 at 500 mA·g −1 over 200 cycles), and impressive rate performance (640 mAh·g −1 at 2,000 mA·g −1 ) for lithium ion batteries (LIBs). This work could provide a potential strategy for improving intrinsic conductivity of transition metal oxides as high-performance anodes for LIBs.

• Publisher: Tsinghua University Press
• Subject: Anodes / Atomic/Molecular Structure and Spectra / Biomedicine / Biotechnology / Chemistry and Materials Science / Condensed Matter Physics / Conductivity / Density functional theory / Doping / Kinetics / Lithium / Lithium-ion batteries / Low temperature / Materials Science / Metal oxides / Molybdates / Nanorods / Nanotechnology / Nickel compounds / Phosphating (coating) / Phosphorus / Rechargeable batteries / Research Article / Specific capacity / Transition metal oxides