Journal Article

Moisture and Glass Transition Temperature Kinetics of Ambient-Cured Carbon/Epoxy Composites

Karbhari, Vistasp M., Hassanpour, Behnaz

2023

Overview

Carbon fiber reinforced polymer composites are widely used in the rehabilitation, repair, and strengthening of civil, marine, and naval infrastructure and structural systems. In these applications, they are exposed to a range of exposure conditions, including humidity and immersion, which are known to affect the durability of the resin and the fiber–matrix interface over long periods of time. This paper presents results of long-term hygrothermal aging of wet layup carbon/epoxy composites including through acceleration by temperature focusing on the development of a comprehensive understanding of moisture uptake kinetics and its effects on glass transition temperature and interface and inter-/intra-laminar dominated performance characteristics. A two-phase model for uptake that incorporates both diffusion- and relaxation-/deterioration-dominated regimes, as well as a transition regime, is shown to describe uptake well. The inclusion of damage terms to the diffusion and relaxation coefficients is seen to capture changes well, with the effective diffusion and relaxation coefficients increasing with fiber volume fraction and temperature. Effects of uptake, including at elevated temperatures, reflective of accelerated aging, on glass transition temperature and flexural strength are correlated, emphasizing a three-stage progression of overall response in line with the moisture uptake changes. The drop in glass transition temperature per percent increase in moisture uptake was seen to range from a low of 4.38% per % increase in moisture content, for the highest volume fraction at the highest temperature, to a high of 6.95% per % increase in moisture content, for the intermediate volume fraction at the lowest temperature. The composites with heavier fabric showed the greatest drop in both glass transition temperature and flexural strength, indicating a level of correlation between these characteristics as well. It is shown that both glass transition temperature and flexural strength show steep initial decreases, followed by a regime with slower decrease and, then, an asymptotic or near-asymptotic response with time of immersion, suggesting a close correlation with moisture uptake, which forms the basis for future modeling.

• Publisher: MDPI AG
• Subject: Asymptotic properties / Carbon fiber reinforced plastics / Carbon fibers / Carbon-epoxy composites / Chemical properties / Chemical reaction, Rate of / Correlation / Epoxy resins / Fiber composites / Fiber reinforced polymers / Fiber volume fraction / Fiber-matrix interfaces / Flexural strength / Glass / Glass transition temperature / High temperature / Humidity / Kinetics / Materials research / Mathematical models / Moisture / Moisture content / Polymer matrix composites / Polymeric composites / Polymers / Submerging / Temperature / Thermal properties / Transition temperature