Journal Article

Microstructure and mechanical properties of carbon graphite composites reinforced by carbon nanofibers

Liu, Tianhua, Huang, Xia, Gong, Pei, Wu, Guangning, Chen, Jian, Jiang, Jizhou, Liu, Ping, Chen, Yixing, Tu, Chuanjun, Liu, Yanli

2023

Overview

Renewed interest in the reinforced carbon graphite composites has intrigued the community in the advanced materials fields. In this work, we present a simple carbon nanofibers reinforced carbon graphite composites synthetic method by incorporating mixture of coal tar pitch, synthetic graphite, pitch coke and the dispersion liquid of carbon nanofibers via liquid-phase mixing process. The impact of carbon nanofiber utilization on the microstructures and mechanical properties of carbon graphite composites are studied systematically. The covalent surface modification of carbon nanofibers effectively improves its microstructure and thereby promotes the carbon graphite composites’ dispersion behavior. We propose that a small amount of carbon nanofibers could promote the carbonization process of carbon graphite composites, facilitating the densification of carbon graphite composites and reducing the undesired open porosity. The amount of 0.7 wt % of carbon nanofiber concentration allows the enhancement of bend and compressive strength of carbon graphite composites up to 36.50 MPa and 60.46 MPa, increased by 167.9% and 146.9% compared with the pure carbon graphite composite, respectively. Our findings can be rationalized due to the improvement in the mechanical strength of carbon graphite composites could be attributed due to pull-out of carbon nanofibers from the matrix and bridging effect across the crack pores within the matrix.

• Publisher: Springer Nature Singapore,Springer Nature B.V
• Subject: Bend strength / Carbon / Carbon fibers / Characterization and Evaluation of Materials / Chemistry and Materials Science / Coal tar / Composite materials / Compressive strength / Densification / Dispersion / Graphite / Heat conductivity / Liquid phases / Materials Engineering / Materials Science / Mechanical properties / Microstructure / Nanofibers / Nanotechnology / Original Article / Oxidation / Pitch (material) / Porosity / Raw materials / Scanning electron microscopy / Spectrum analysis