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Improving interface quality for 1-cm2 all-perovskite tandem solar cells
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Journal Article
Improving interface quality for 1-cm2 all-perovskite tandem solar cells
2023
Overview
All-perovskite tandem solar cells provide high power conversion efficiency at a low cost
1
–
4
. Rapid efficiency improvement in small-area (<0.1 cm
2
) tandem solar cells has been primarily driven by advances in low-bandgap (approximately 1.25 eV) perovskite bottom subcells
5
–
7
. However, unsolved issues remain for wide-bandgap (> 1.75 eV) perovskite top subcells
8
, which at present have large voltage and fill factor losses, particularly for large-area (>1 cm
2
) tandem solar cells. Here we develop a self-assembled monolayer of (4-(7
H
-dibenzo[
c,g
]carbazol-7-yl)butyl)phosphonic acid as a hole-selective layer for wide-bandgap perovskite solar cells, which facilitates subsequent growth of high-quality wide-bandgap perovskite over a large area with suppressed interfacial non-radiative recombination, enabling efficient hole extraction. By integrating (4-(7
H
-dibenzo[
c,g
]carbazol-7-yl)butyl)phosphonic acid in devices, we demonstrate a high open-circuit voltage (
V
OC
) of 1.31 V in a 1.77-eV perovskite solar cell, corresponding to a very low
V
OC
deficit of 0.46 V (with respect to the bandgap). With these wide-bandgap perovskite subcells, we report 27.0% (26.4% certified stabilized) monolithic all-perovskite tandem solar cells with an aperture area of 1.044 cm
2
. The certified tandem cell shows an outstanding combination of a high
V
OC
of 2.12 V and a fill factor of 82.6%. Our demonstration of the large-area tandem solar cells with high certified efficiency is a key step towards scaling up all-perovskite tandem photovoltaic technology.
A self-assembled monolayer of (4-(7
H
-dibenzo[
c,g
]carbazol-7-yl)butyl)phosphonic acid is integrated in wide-bandgap perovskite solar cells, which enables a high power conversion efficiency and low open-circuit voltage deficiency, as well as efficient centimetre-scale all-perovskite tandem solar cells.
Publisher
Nature Publishing Group UK,Nature Publishing Group
Subject
