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Cl, Br, B, Li, and noble gases isotopes to study the origin and evolution of deep groundwater in sedimentary basins: a review
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Cl, Br, B, Li, and noble gases isotopes to study the origin and evolution of deep groundwater in sedimentary basins: a review
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Cl, Br, B, Li, and noble gases isotopes to study the origin and evolution of deep groundwater in sedimentary basins: a review
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Journal Article
Cl, Br, B, Li, and noble gases isotopes to study the origin and evolution of deep groundwater in sedimentary basins: a review
2022
Overview
Deep groundwater characteristics provide valuable information on oil and gas extraction and evolution of hydrosphere, and nonmetallic and metallic elements in deep groundwater are raising industrial interest. There is therefore a need for a better understanding of the origin and evolution of deep groundwater in large sedimentary basins, e.g., by using non-traditional isotopes. Here, we review the constraints of isotopes of chloride (Cl), bromine (Br), boron (B), lithium (Li), helium (He), neon (Ne), and argon (Ar) on the origin and evolution of deep groundwater in large sedimentary basins. In deep groundwater, δ
37
Cl ranges from −1.96 to + 2.07‰, δ
81
Br from −1.50 to + 3.35‰, δ
11
B from + 1.10 to + 39.99‰, and δ
7
Li from −1.00 to + 31.80‰. These values either overlap or are different compared to those in freshwater, e.g., meteoric water, river water and shallow groundwater, hydrothermal fluid, seawater, subsurface brine, lake sediment, or mineral. Noble gas isotopes such as
3
He/
4
He,
4
He/
20
Ne, and
36
Ar/
40
Ar are also effective tracers for deep groundwater evolution. Integrating multiple non-traditional isotopes allows to study dissolution, sedimentation, evaporation, and mixing of different waters in deep aquifers.
