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Cycling performance of layered oxide cathode materials for sodium-ion batteries
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Cycling performance of layered oxide cathode materials for sodium-ion batteries
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Journal Article
Cycling performance of layered oxide cathode materials for sodium-ion batteries
2024
Overview
Layered oxide is a promising cathode material for sodium-ion batteries because of its high-capacity, high operating voltage, and simple synthesis. Cycling performance is an important criterion for evaluating the application prospects of batteries. However, facing challenges, including phase transitions, ambient stability, side reactions, and irreversible anionic oxygen activity, the cycling performance of layered oxide cathode materials still cannot meet the application requirements. Therefore, this review proposes several strategies to address these challenges. First, bulk doping is introduced from three aspects: cationic single doping, anionic single doping, and multi-ion doping. Second, homogeneous surface coating and concentration gradient modification are reviewed. In addition, methods such as mixed structure design, particle engineering, high-entropy material construction, and integrated modification are proposed. Finally, a summary and outlook provide a new horizon for developing and modifying layered oxide cathode materials.
Publisher
University of Science and Technology Beijing,Springer Nature B.V,School of Metallurgical and Ecological Engineering, University of Science and Technology Beijing, Beijing 100083, China,Beijing Key Laboratory for Green Recovery and Extraction of Rare and Precious Metals, University of Science and Technology Beijing, Beijing 100083, China,State Key Laboratory of Advanced Metallurgy, University of Science and Technology Beijing, Beijing 100083, China
