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Energy consumption of electrooxidation systems with boron-doped diamond electrodes in the pulse current mode
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Energy consumption of electrooxidation systems with boron-doped diamond electrodes in the pulse current mode
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Journal Article
Energy consumption of electrooxidation systems with boron-doped diamond electrodes in the pulse current mode
2013
Overview
A pulse current technique was conducted in a boron-doped diamond （BDD） anode system for electrochemical waste- water treatment. Due to the strong generation and weak absorption of hydroxyl radicals on the diamond surface, the BDD elec- trode possesses a powerful capability of electrochemical oxidation of organic compounds, especially in the pulse current mode. The influences of pulse current parameters such as current density, pulse duty cycle, and frequency were investigated in terms of chemical oxygen demand （COD） removal, average current efficiency, and specific energy consumption. The results demon- strated that the relatively high COD removal and low specific energy consumption were obtained simultaneously only if the current density or pulse duty cycle was adjusted to a reasonable value. Increasing the frequency slightly enhanced the COD re- moval and average current efficiency. A pulse-BDD anode system showed a stronger energy saving ability than a constant-BDD anode system when the electrochemical oxidation of phenol of the two systems was compared. The results prove that the pulse current technique is more cost-effective and more suitable for a BDD anode system for real wastewater treatment. A kinetic analysis was presented to explain the above results.
Publisher
University of Science and Technology Beijing,Springer Nature B.V,Institute of Advanced Materials and Technology, University of Science and Technology Beijing, Beijing 100083, China%Institute of Manufacturing Engineering, National University of Sciences & Technology(NUST), Habib Ibrahim Rehamat ullah Road, Karachi 75350,Pakistan
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