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Dynamic multimodal holograms of conjugated organogels via dithering mask lithography
Dynamic multimodal holograms of conjugated organogels via dithering mask lithography
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Dynamic multimodal holograms of conjugated organogels via dithering mask lithography
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Dynamic multimodal holograms of conjugated organogels via dithering mask lithography
Dynamic multimodal holograms of conjugated organogels via dithering mask lithography

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Dynamic multimodal holograms of conjugated organogels via dithering mask lithography
Dynamic multimodal holograms of conjugated organogels via dithering mask lithography
Journal Article

Dynamic multimodal holograms of conjugated organogels via dithering mask lithography

2021
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Overview
Polymeric materials have been used to realize optical systems that, through periodic variations of their structural or optical properties, interact with light-generating holographic signals. Complex holographic systems can also be dynamically controlled through exposure to external stimuli, yet they usually contain only a single type of holographic mode. Here, we report a conjugated organogel that reversibly displays three modes of holograms in a single architecture. Using dithering mask lithography, we realized two-dimensional patterns with varying cross-linking densities on a conjugated polydiacetylene. In protic solvents, the organogel contracts anisotropically to develop optical and structural heterogeneities along the third dimension, displaying holograms in the form of three-dimensional full parallax signals, both in fluorescence and bright-field microscopy imaging. In aprotic solvents, these heterogeneities diminish as organogels expand, recovering the two-dimensional periodicity to display a third hologram mode based on iridescent structural colours. Our study presents a next-generation hologram manufacturing method for multilevel encryption technologies. Periodic patterns with varying cross-linking densities are realized in conjugated polydiacetylene films, creating multiple holographic images—all dynamically responsive to exposure to various solvents—simultaneously in the same polymeric structures.