Asset Details
Do you wish to reserve the book?
Structural and electrochemical properties of ternary solid polymer electrolytes based on PVA:CS:FSG doped with sodium thiocyanate
Hey, we have placed the reservation for you!
By the way, why not check out events that you can attend while you pick your title.
Oops! Something went wrong.
Looks like we were not able to place the reservation. Kindly try again later.
Are you sure you want to remove the book from the shelf?
Structural and electrochemical properties of ternary solid polymer electrolytes based on PVA:CS:FSG doped with sodium thiocyanate
Do you wish to request the book?
Structural and electrochemical properties of ternary solid polymer electrolytes based on PVA:CS:FSG doped with sodium thiocyanate
Please be aware that the book you have requested cannot be checked out. If you would like to checkout this book, you can reserve another copy
We have requested the book for you!
Your request is successful and it will be processed during the Library working hours. Please check the status of your request in My Requests.
Oops! Something went wrong.
Looks like we were not able to place your request. Kindly try again later.
Journal Article
Structural and electrochemical properties of ternary solid polymer electrolytes based on PVA:CS:FSG doped with sodium thiocyanate
2025
Overview
Biodegradable solid polymer electrolytes (BSPEs) have gained significant attention due to their exceptional processability, safety, and flexibility. This work presents the development of sodium ion (Na +) conducting ternary blended (BSPEs) using a standard solution casting technique. Fourier transform infrared spectroscopy (FTIR) and X-ray diffraction (XRD) validated the complete salt dissociation and demonstrated the formation of polymer-salt complexes. The deconvoluted XRD spectra revealed the degree of crystallinity (
) of electrolytes where the sample incorporated 40 wt% of NaSCN salt content (STC4) was found to be the lowest
value. The deconvoluted FTIR spectra were used to estimate ionic transport parameters of diffusion coefficient (
), ion mobility (
), and carrier density (
). Ionic conductivity and electrical properties of electrolyte samples were investigated by electrochemical impedance spectroscopy (EIS). The EIS results were fitted with electrical equivalent circuits to understand the electrical behavior of the films. The highest DC conductivity value (
) of (2.74 × 10
−6
S/cm) was achieved for the STC4 sample, attributed to its highest amorphous region and carrier density. The dielectric studies proved beneficial in distinguishing the areas attributed to molecular polarizations and electrodes. The reduction of relaxation time is indicated by shifting loss tangent peaks (tan δ) toward high frequency ranges. According to dielectric relaxation studies, the appearance of peaks confirmed non-Debye type behavior. Distinct areas attributed to the effects of electrode polarization and (
) are seen in AC conductivity (
) spectra.
Publisher
Nature Publishing Group UK,Nature Portfolio
