Journal Article

Yttrium‐ and nitrogen‐doped NiCo phosphide nanosheets for high‐efficiency water electrolysis

Chen, Wei, Ostrikov, Kostya (Ken), Chen, Guangliang, Guo, Yingchun, Xiang, Huiyang, Li, Tongtong, Chen, Zhuoyi, Huang, Jun

2024

Overview

Engineering high‐performance and low‐cost bifunctional catalysts for H2 (hydrogen evolution reaction [HER]) and O2 (oxygen evolution reaction [OER]) evolution under industrial electrocatalytic conditions remains challenging. Here, for the first time, we use the stronger electronegativity of a rare‐Earth yttrium ion (Y3+) to induce in situ NiCo‐layered double‐hydroxide nanosheets from NiCo foam (NCF) treated by a dielectric barrier discharge plasma NCF (PNCF), and then obtain nitrogen‐doped YNiCo phosphide (N‐YNiCoP/PNCF) after the phosphating process using radiofrequency plasma in nitrogen. The obtained N‐YNiCoP/PNCF has a large specific surface area, rich heterointerfaces, and an optimized electronic structure, inducing high electrocatalytic activity in HER (331 mV vs. 2000 mA cm−2) and OER (464 mV vs. 2000 mA cm−2) reactions in 1 M KOH electrolyte. X‐ray absorption spectroscopy and density functional theory quantum chemistry calculations reveal that the coordination number of CoNi decreased with the incorporation of Y atoms, which induce much shorter bonds of Ni and Co ions and promote long‐term stability of N‐YNiCoP in HER and OER under the simulated industrial conditions. Meanwhile, the CoN‐YP5 heterointerface formed by plasma N‐doping is the active center for overall water splitting. This work expands the applications of rare‐Earth elements in engineering bifunctional electrocatalysts and provides a new avenue for designing high‐performance transition‐metal‐based catalysts in the renewable energy field. A N‐YNiCoP nanosheet structure is in situ engineered on Ni–Co foam using a dual‐plasma technique and acts as a bifunctional electrocatalyst for water splitting. The formed rich heterointerfaces and N‐doping effectively tune the electronic states of the catalyst, resulting in high hydrogen evolution reaction and oxygen evolution reaction performances in an alkaline medium at an industrial‐scale current density of 2000 mA cm−2.

• Publisher: John Wiley & Sons, Inc,Wiley
• Subject: Absorption spectroscopy / Atomic properties / Catalysts / Chemical bonds / Clean technology / Coordination numbers / Density functional theory / Dielectric barrier discharge / Dielectric strength / Electrocatalysts / Electrodes / Electrolysis / Electronegativity / Electronic structure / Electrons / Energy / Ethanol / Evolution / Hydrogen / Hydrogen evolution reactions / Intermetallic compounds / Metals / Nanosheets / Nitrates / Nitrogen / overall water splitting / Oxygen evolution reactions / Phosphating (coating) / Phosphides / Plasma / plasma etching / plasma N‐doping / Quantum chemistry / Radio frequency / rare‐earth electrocatalyst / Renewable energy / Temperature / Water / Water splitting / Yttrium / yttrium incorporation