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n-Hexyl Laurate and Fourteen Related Fatty Acid Esters: New Secretory Compounds from the Julid Millipede, Anaulaciulus sp
by
Tanabe, Tsutomu
, Kuwahara, Yasumasa
, Shimizu, Nobuhiro
, Yakumaru, Ryota
in
Acids
/ Agriculture
/ alcohols
/ Alcohols - chemistry
/ Animals
/ Arthropods
/ Arthropods - chemistry
/ Arthropods - classification
/ Arthropods - metabolism
/ benzoquinones
/ Biochemistry
/ Biological Microscopy
/ Biological Products
/ Biological Products - chemistry
/ Biological Products - metabolism
/ Biomedical and Life Sciences
/ Chemical ecology
/ chemistry
/ classification
/ Ecology
/ Entomology
/ Esters
/ fatty acid esters
/ Fatty acids
/ Female
/ Julida
/ Julidae
/ Lauric Acids
/ Lauric Acids - chemistry
/ Lauric Acids - metabolism
/ Life Sciences
/ Male
/ metabolism
/ saturated fatty acids
/ secretion
/ Volatilization
2012
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n-Hexyl Laurate and Fourteen Related Fatty Acid Esters: New Secretory Compounds from the Julid Millipede, Anaulaciulus sp
by
Tanabe, Tsutomu
, Kuwahara, Yasumasa
, Shimizu, Nobuhiro
, Yakumaru, Ryota
in
Acids
/ Agriculture
/ alcohols
/ Alcohols - chemistry
/ Animals
/ Arthropods
/ Arthropods - chemistry
/ Arthropods - classification
/ Arthropods - metabolism
/ benzoquinones
/ Biochemistry
/ Biological Microscopy
/ Biological Products
/ Biological Products - chemistry
/ Biological Products - metabolism
/ Biomedical and Life Sciences
/ Chemical ecology
/ chemistry
/ classification
/ Ecology
/ Entomology
/ Esters
/ fatty acid esters
/ Fatty acids
/ Female
/ Julida
/ Julidae
/ Lauric Acids
/ Lauric Acids - chemistry
/ Lauric Acids - metabolism
/ Life Sciences
/ Male
/ metabolism
/ saturated fatty acids
/ secretion
/ Volatilization
2012
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n-Hexyl Laurate and Fourteen Related Fatty Acid Esters: New Secretory Compounds from the Julid Millipede, Anaulaciulus sp
by
Tanabe, Tsutomu
, Kuwahara, Yasumasa
, Shimizu, Nobuhiro
, Yakumaru, Ryota
in
Acids
/ Agriculture
/ alcohols
/ Alcohols - chemistry
/ Animals
/ Arthropods
/ Arthropods - chemistry
/ Arthropods - classification
/ Arthropods - metabolism
/ benzoquinones
/ Biochemistry
/ Biological Microscopy
/ Biological Products
/ Biological Products - chemistry
/ Biological Products - metabolism
/ Biomedical and Life Sciences
/ Chemical ecology
/ chemistry
/ classification
/ Ecology
/ Entomology
/ Esters
/ fatty acid esters
/ Fatty acids
/ Female
/ Julida
/ Julidae
/ Lauric Acids
/ Lauric Acids - chemistry
/ Lauric Acids - metabolism
/ Life Sciences
/ Male
/ metabolism
/ saturated fatty acids
/ secretion
/ Volatilization
2012
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n-Hexyl Laurate and Fourteen Related Fatty Acid Esters: New Secretory Compounds from the Julid Millipede, Anaulaciulus sp
Journal Article
n-Hexyl Laurate and Fourteen Related Fatty Acid Esters: New Secretory Compounds from the Julid Millipede, Anaulaciulus sp
2012
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Overview
A total of fifteen saturated fatty acid esters were newly identified from the secretions of an unidentified
Anaulaciulus
sp. (Julida: Julidae). The fatty acid components of the esters were composed of normal chain acids (from C
10
to C
14
) and of branched chain acids (from iso-C
12
to iso-C
15
and anteiso-C
15
). The alcohol moieties were all composed of normal chain alcohols varying from
n
-butanol to
n
-octanol. The most abundant component found in the total esters was
n
-hexyl laurate (64.7%). Novel compounds identified from the millipede secretion extracts include six branched iso- and anteiso-fatty esters, an odd-numbered C
11
-fatty acid ester, a C
13
-fatty acid ester, and a C
7
-alcohol ester, all of which were previously undescribed natural products. In addition, a characteristic mixture of benzoquinones, such as 2-methyl-1,4-benzoquinone, 2-methoxy-3-methyl-1,4-benzoquinone, 2,3-dimethoxy-1,4-benzoquinone, 2-methoxy-6-methyl-1,4-benzoquinone, and 2,3-dimethoxy-5-methyl-1,4-benzoquinone were identified from the secretions, together with trace amounts of 1,4-benzoquinone.
Publisher
Springer-Verlag,Springer Nature B.V
Subject
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