Asset Details
Do you wish to reserve the book?
Approaching isotropic charge transport of n-type organic semiconductors with bulky substituents
Hey, we have placed the reservation for you!
By the way, why not check out events that you can attend while you pick your title.
Oops! Something went wrong.
Looks like we were not able to place the reservation. Kindly try again later.
Are you sure you want to remove the book from the shelf?
Approaching isotropic charge transport of n-type organic semiconductors with bulky substituents
Do you wish to request the book?
Approaching isotropic charge transport of n-type organic semiconductors with bulky substituents
Please be aware that the book you have requested cannot be checked out. If you would like to checkout this book, you can reserve another copy
We have requested the book for you!
Your request is successful and it will be processed during the Library working hours. Please check the status of your request in My Requests.
Oops! Something went wrong.
Looks like we were not able to place your request. Kindly try again later.
Journal Article
Approaching isotropic charge transport of n-type organic semiconductors with bulky substituents
2021
Overview
Benzo[
de
]isoquinolino[1,8-
gh
]quinolinetetracarboxylic diimide (BQQDI) is an n-type organic semiconductor that has shown unique multi-fold intermolecular hydrogen-bonding interactions, leading to aggregated structures with excellent charge transports and electron mobility properties. However, the strong intermolecular anchoring of BQQDI presents challenges for fine-tuning the molecular assembly and improving the semiconducting properties. Herein, we report the design and synthesis of two BQQDI derivatives with phenyl- and cyclohexyl substituents (Ph–BQQDI and Cy
6
–BQQDI), where the two organic semiconductors show distinct molecular assemblies and degrees of intermolecular orbital overlaps. In addition, the difference in their packing motifs leads to strikingly different band structures that give rise to contrasting charge-transport capabilities. More specifically, Cy
6
–BQQDI bearing bulky substituents exhibits isotropic intermolecular orbital overlaps resulting in equal averaged transfer integrals in both π-π stacking directions, even when dynamic disorders are taken into account; whereas Ph–BQQDI exhibits anisotropic averaged transfer integrals in these directions. As a result, Cy
6
–BQQDI shows excellent device performances in both single-crystalline and polycrystalline thin-film organic field-effect transistors up to 2.3 and 1.0 cm
2
V
−1
s
−1
, respectively.
n-type organic semiconductors exhibiting two-dimensional isotropic charge transport are rarely reported. Here the authors show that using bulky substituents, BQQDI demonstrates near-isotropic charge transport, resilience to dynamic disorder, as well as high electron mobility both in single- and polycrystalline thin-film transistors.
Publisher
Nature Publishing Group UK,Nature Publishing Group,Nature Portfolio
Subject
