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Modulating electrolyte structure for ultralow temperature aqueous zinc batteries
by
Zhang, Qiu
, Li, Lin
, Ma, Yilin
, Wan, Fang
, Lu, Yong
, Chen, Jun
, Zhang, Kai
in
140/133
/ 639/301/299/891
/ 639/4077/4079/891
/ Aqueous electrolytes
/ Cost analysis
/ Earth surface
/ Electrolytes
/ Energy storage
/ Humanities and Social Sciences
/ Low cost
/ Low temperature
/ multidisciplinary
/ Polyanilines
/ Rechargeable batteries
/ Safety
/ Science
/ Science (multidisciplinary)
/ Storage batteries
/ Surface temperature
/ Transition temperature
/ Transition temperatures
/ Zinc chloride
2020
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Modulating electrolyte structure for ultralow temperature aqueous zinc batteries
by
Zhang, Qiu
, Li, Lin
, Ma, Yilin
, Wan, Fang
, Lu, Yong
, Chen, Jun
, Zhang, Kai
in
140/133
/ 639/301/299/891
/ 639/4077/4079/891
/ Aqueous electrolytes
/ Cost analysis
/ Earth surface
/ Electrolytes
/ Energy storage
/ Humanities and Social Sciences
/ Low cost
/ Low temperature
/ multidisciplinary
/ Polyanilines
/ Rechargeable batteries
/ Safety
/ Science
/ Science (multidisciplinary)
/ Storage batteries
/ Surface temperature
/ Transition temperature
/ Transition temperatures
/ Zinc chloride
2020
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While trying to remove the title from your shelf something went wrong :( Kindly try again later!
Do you wish to request the book?
Modulating electrolyte structure for ultralow temperature aqueous zinc batteries
by
Zhang, Qiu
, Li, Lin
, Ma, Yilin
, Wan, Fang
, Lu, Yong
, Chen, Jun
, Zhang, Kai
in
140/133
/ 639/301/299/891
/ 639/4077/4079/891
/ Aqueous electrolytes
/ Cost analysis
/ Earth surface
/ Electrolytes
/ Energy storage
/ Humanities and Social Sciences
/ Low cost
/ Low temperature
/ multidisciplinary
/ Polyanilines
/ Rechargeable batteries
/ Safety
/ Science
/ Science (multidisciplinary)
/ Storage batteries
/ Surface temperature
/ Transition temperature
/ Transition temperatures
/ Zinc chloride
2020
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Modulating electrolyte structure for ultralow temperature aqueous zinc batteries
Journal Article
Modulating electrolyte structure for ultralow temperature aqueous zinc batteries
2020
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Overview
Rechargeable aqueous batteries are an up-and-coming system for potential large-scale energy storage due to their high safety and low cost. However, the freeze of aqueous electrolyte limits the low-temperature operation of such batteries. Here, we report the breakage of original hydrogen-bond network in ZnCl
2
solution by modulating electrolyte structure, and thus suppressing the freeze of water and depressing the solid-liquid transition temperature of the aqueous electrolyte from 0 to –114 °C. This ZnCl
2
-based low-temperature electrolyte renders polyaniline||Zn batteries available to operate in an ultra-wide temperature range from –90 to +60 °C, which covers the earth surface temperature in record. Such polyaniline||Zn batteries are robust at –70 °C (84.9 mA h g
−1
) and stable during over 2000 cycles with ~100% capacity retention. This work significantly provides an effective strategy to propel low-temperature aqueous batteries via tuning the electrolyte structure and widens the application range of temperature adaptation of aqueous batteries.
Rechargeable aqueous batteries are promising for potential large-scale energy storage due to their high safety and low cost. Here the authors analyse a zinc chloride based low-temperature electrolyte for improving practicability of the aqueous batteries.
Publisher
Nature Publishing Group UK,Nature Publishing Group,Nature Portfolio
Subject
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