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Nitrogen‐Doped Graphene‐Like Carbon Intercalated MXene Heterostructure Electrodes for Enhanced Sodium‐ and Lithium‐Ion Storage
by
Wu, Tao
, Prenger, Kaitlyn
, Urban, Jeffrey J.
, Presser, Volker
, Jiang, De‐en
, Naguib, Michael
, Husmann, Samantha
, Misra, Sudhajit
, Unocic, Raymond R.
, Liang, Kun
, Dun, Chaochao
in
Annealing
/ Batteries
/ Carbon
/ Dopamine
/ Electrodes
/ Electrons
/ Energy storage
/ Graphene
/ heterostructures
/ Metal oxides
/ MXene
/ Oxidation
/ Temperature
2024
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Nitrogen‐Doped Graphene‐Like Carbon Intercalated MXene Heterostructure Electrodes for Enhanced Sodium‐ and Lithium‐Ion Storage
by
Wu, Tao
, Prenger, Kaitlyn
, Urban, Jeffrey J.
, Presser, Volker
, Jiang, De‐en
, Naguib, Michael
, Husmann, Samantha
, Misra, Sudhajit
, Unocic, Raymond R.
, Liang, Kun
, Dun, Chaochao
in
Annealing
/ Batteries
/ Carbon
/ Dopamine
/ Electrodes
/ Electrons
/ Energy storage
/ Graphene
/ heterostructures
/ Metal oxides
/ MXene
/ Oxidation
/ Temperature
2024
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Nitrogen‐Doped Graphene‐Like Carbon Intercalated MXene Heterostructure Electrodes for Enhanced Sodium‐ and Lithium‐Ion Storage
by
Wu, Tao
, Prenger, Kaitlyn
, Urban, Jeffrey J.
, Presser, Volker
, Jiang, De‐en
, Naguib, Michael
, Husmann, Samantha
, Misra, Sudhajit
, Unocic, Raymond R.
, Liang, Kun
, Dun, Chaochao
in
Annealing
/ Batteries
/ Carbon
/ Dopamine
/ Electrodes
/ Electrons
/ Energy storage
/ Graphene
/ heterostructures
/ Metal oxides
/ MXene
/ Oxidation
/ Temperature
2024
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Nitrogen‐Doped Graphene‐Like Carbon Intercalated MXene Heterostructure Electrodes for Enhanced Sodium‐ and Lithium‐Ion Storage
Journal Article
Nitrogen‐Doped Graphene‐Like Carbon Intercalated MXene Heterostructure Electrodes for Enhanced Sodium‐ and Lithium‐Ion Storage
2024
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Overview
MXene is investigated as an electrode material for different energy storage systems due to layered structures and metal‐like electrical conductivity. Experimental results show MXenes possess excellent cycling performance as anode materials, especially at large current densities. However, the reversible capacity is relatively low, which is a significant barrier to meeting the demands of industrial applications. This work synthesizes N‐doped graphene‐like carbon (NGC) intercalated Ti3C2Tx (NGC‐Ti3C2Tx) van der Waals heterostructure by an in situ method. The as‐prepared NGC‐Ti3C2Tx van der Waals heterostructure is employed as sodium‐ion and lithium‐ion battery electrodes. For sodium‐ion batteries, a reversible specific capacity of 305 mAh g−1 is achieved at a specific current of 20 mA g−1, 2.3 times higher than that of Ti3C2Tx. For lithium‐ion batteries, a reversible capacity of 400 mAh g−1 at a specific current of 20 mA g−1 is 1.5 times higher than that of Ti3C2Tx. Both sodium‐ion and lithium‐ion batteries made from NGC‐Ti3C2Tx shows high cycling stability. The theoretical calculations also verify the remarkable improvement in battery capacity within the NGC‐Ti3C2O2 system, attributed to the additional adsorption of working ions at the edge states of NGC. This work offers an innovative way to synthesize a new van der Waals heterostructure and provides a new route to improve the electrochemical performance significantly.
Multilayer MXenes, noted for their metal‐like conductivity and layered structure, shows limited reversible capacity in energy storage. To overcome this, N‐doped graphene‐like carbon (NGC) is confined in between Ti3C2Tx layers to form a heterostructure. This structure significantly improves the capacity and stability of sodium‐ion and lithium‐ion batteries, offering a promising method to enhance electrochemical performance.
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