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Self-diffusion in garnet-type Li7La3Zr2O12 solid electrolytes
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Self-diffusion in garnet-type Li7La3Zr2O12 solid electrolytes
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Journal Article
Self-diffusion in garnet-type Li7La3Zr2O12 solid electrolytes
2021
Overview
Tetragonal garnet-type Li
7
La
3
Zr
2
O
12
is an important candidate solid electrolyte for all-solid-state lithium ion batteries because of its high ionic conductivity and large electrochemical potential window. Here we employ atomistic simulation methods to show that the most favourable disorder process in Li
7
La
3
Zr
2
O
12
involves loss of Li
2
O resulting in lithium and oxygen vacancies, which promote vacancy mediated self-diffusion. The activation energy for lithium migration (0.45 eV) is much lower than that for oxygen (1.65 eV). Furthermore, the oxygen migration activation energy reveals that the oxygen diffusion in this material can be facilitated at higher temperatures once oxygen vacancies form.
Publisher
Springer Science and Business Media LLC,Nature Publishing Group UK,Nature Publishing Group
Subject
