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Journal Article
Proton switching molecular magnetoelectricity
2021
Overview
The convergence of proton conduction and multiferroics is generating a compelling opportunity to achieve strong magnetoelectric coupling and magneto-ionics, offering a versatile platform to realize molecular magnetoelectrics. Here we describe machine learning coupled with additive manufacturing to accelerate the design strategy for hydrogen-bonded multiferroic macromolecules accompanied by strong proton dependence of magnetic properties. The proton switching magnetoelectricity occurs in three-dimensional molecular heterogeneous solids. It consists of a molecular magnet network as proton reservoir to modulate ferroelectric polarization, while molecular ferroelectrics charging proton transfer to reversibly manipulate magnetism. The magnetoelectric coupling induces a reversible 29% magnetization control at ferroelectric phase transition with a broad thermal hysteresis width of 160 K (192 K to 352 K), while a room-temperature reversible magnetic modulation is realized at a low electric field stimulus of 1 kV cm
−1
. The findings of electrostatic proton transfer provide a pathway of proton mediated magnetization control in hierarchical molecular multiferroics.
Compared to inorganic materials, the magnetoelectric coupling in macromolecules is still hidden. Here, the authors describe machine learning coupled with additive manufacturing to accelerate the discovery of multiferroic macromolecules with a proton-mediated magnetoelectric coupling effect.
Publisher
Nature Publishing Group UK,Nature Publishing Group,Nature Portfolio
Subject
