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The coupling and competition of crystallization and phase separation, correlating thermodynamics and kinetics in OPV morphology and performances
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The coupling and competition of crystallization and phase separation, correlating thermodynamics and kinetics in OPV morphology and performances
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Journal Article
The coupling and competition of crystallization and phase separation, correlating thermodynamics and kinetics in OPV morphology and performances
2021
Overview
The active layer morphology transition of organic photovoltaics under non-equilibrium conditions are of vital importance in determining the device power conversion efficiency and stability; however, a general and unified picture on this issue has not been well addressed. Using combined in situ and ex situ morphology characterizations, morphological parameters relating to kinetics and thermodynamics of morphology evolution are extracted and studied in model systems under thermal annealing. The coupling and competition of crystallization and demixing are found to be critical in morphology evolution, phase purification and interfacial orientation. A unified model summarizing different phase diagrams and all possible kinetic routes is proposed. The current observations address the fundamental issues underlying the formation of the complex multi-length scale morphology in bulk heterojunction blends and provide useful morphology optimization guidelines for processing devices with higher efficiency and stability.
Designing efficient blue perovskite LEDs by using mixed halides perovskite is still a challenge, limited mainly by the phase segregation issue. Here, the authors demonstrate in situ fabrication of quasi-2D CsPbClBr2 nanocrystal films with mixed ligands to overcome the constraint.
Publisher
Nature Publishing Group UK,Nature Publishing Group,Nature Portfolio
