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Grain refinement in titanium prevents low temperature oxygen embrittlement
by
Tsuru, Tomohito
, Mitsuhara, Masatoshi
, Zhang, Ruopeng
, Minor, Andrew M.
, Morris, J. W.
, Chong, Yan
, Gholizadeh, Reza
, Gao, Wenqiang
, Tsuji, Nobuhiro
, Inoue, Koji
, Godfrey, Andy
in
119/118
/ 639/301/1023/1026
/ 639/301/1023/303
/ Alloy systems
/ Cryogenic temperature
/ Ductility
/ Elongation
/ Grain boundaries
/ Grain Boundary Segregation
/ Grain refinement
/ Grain size
/ High strength alloys
/ Humanities and Social Sciences
/ Interstitial solutions
/ Low temperature
/ MATERIALS SCIENCE
/ Microstructure
/ multidisciplinary
/ Oxygen
/ Oxygen content
/ Science
/ Science (multidisciplinary)
/ Solution strengthening
/ Strain hardening
/ Titanium
/ Titanium base alloys
/ Ultrafines
2023
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Grain refinement in titanium prevents low temperature oxygen embrittlement
by
Tsuru, Tomohito
, Mitsuhara, Masatoshi
, Zhang, Ruopeng
, Minor, Andrew M.
, Morris, J. W.
, Chong, Yan
, Gholizadeh, Reza
, Gao, Wenqiang
, Tsuji, Nobuhiro
, Inoue, Koji
, Godfrey, Andy
in
119/118
/ 639/301/1023/1026
/ 639/301/1023/303
/ Alloy systems
/ Cryogenic temperature
/ Ductility
/ Elongation
/ Grain boundaries
/ Grain Boundary Segregation
/ Grain refinement
/ Grain size
/ High strength alloys
/ Humanities and Social Sciences
/ Interstitial solutions
/ Low temperature
/ MATERIALS SCIENCE
/ Microstructure
/ multidisciplinary
/ Oxygen
/ Oxygen content
/ Science
/ Science (multidisciplinary)
/ Solution strengthening
/ Strain hardening
/ Titanium
/ Titanium base alloys
/ Ultrafines
2023
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Grain refinement in titanium prevents low temperature oxygen embrittlement
by
Tsuru, Tomohito
, Mitsuhara, Masatoshi
, Zhang, Ruopeng
, Minor, Andrew M.
, Morris, J. W.
, Chong, Yan
, Gholizadeh, Reza
, Gao, Wenqiang
, Tsuji, Nobuhiro
, Inoue, Koji
, Godfrey, Andy
in
119/118
/ 639/301/1023/1026
/ 639/301/1023/303
/ Alloy systems
/ Cryogenic temperature
/ Ductility
/ Elongation
/ Grain boundaries
/ Grain Boundary Segregation
/ Grain refinement
/ Grain size
/ High strength alloys
/ Humanities and Social Sciences
/ Interstitial solutions
/ Low temperature
/ MATERIALS SCIENCE
/ Microstructure
/ multidisciplinary
/ Oxygen
/ Oxygen content
/ Science
/ Science (multidisciplinary)
/ Solution strengthening
/ Strain hardening
/ Titanium
/ Titanium base alloys
/ Ultrafines
2023
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Grain refinement in titanium prevents low temperature oxygen embrittlement
Journal Article
Grain refinement in titanium prevents low temperature oxygen embrittlement
2023
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Overview
Interstitial oxygen embrittles titanium, particularly at cryogenic temperatures, which necessitates a stringent control of oxygen content in fabricating titanium and its alloys. Here, we propose a structural strategy, via grain refinement, to alleviate this problem. Compared to a coarse-grained counterpart that is extremely brittle at 77 K, the uniform elongation of an ultrafine-grained (UFG) microstructure (grain size ~ 2.0 µm) in Ti-0.3wt.%O is successfully increased by an order of magnitude, maintaining an ultrahigh yield strength inherent to the UFG microstructure. This unique strength-ductility synergy in UFG Ti-0.3wt.%O is achieved via the combined effects of diluted grain boundary segregation of oxygen that helps to improve the grain boundary cohesive energy and enhanced dislocation activities that contribute to the excellent strain hardening ability. The present strategy will not only boost the potential applications of high strength Ti-O alloys at low temperatures, but can also be applied to other alloy systems, where interstitial solution hardening results into an undesirable loss of ductility.
Oxygen has long been considered as a detrimental impurity in pure titanium since it can severely deteriorate the ductility. Here, the authors propose a simple, yet effective strategy via grain refinement to solve this long-standing issue, while preserving its potential hardening effect.
Publisher
Nature Publishing Group UK,Nature Publishing Group,Nature Portfolio
Subject
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