Asset Details
Do you wish to reserve the book?
Synthesis of Imido Analogs of the Uranyl Ion
Hey, we have placed the reservation for you!
By the way, why not check out events that you can attend while you pick your title.
Oops! Something went wrong.
Looks like we were not able to place the reservation. Kindly try again later.
Are you sure you want to remove the book from the shelf?
Synthesis of Imido Analogs of the Uranyl Ion
Do you wish to request the book?
Synthesis of Imido Analogs of the Uranyl Ion
Please be aware that the book you have requested cannot be checked out. If you would like to checkout this book, you can reserve another copy
We have requested the book for you!
Your request is successful and it will be processed during the Library working hours. Please check the status of your request in My Requests.
Oops! Something went wrong.
Looks like we were not able to place your request. Kindly try again later.
Journal Article
Synthesis of Imido Analogs of the Uranyl Ion
2005
Overview
Here we describe the synthesis of two imido analogs of the uranyl ion, UO²⁺₂, in which the oxygens are replaced by divalent alkyl or aryl nitrogen groups: U(N[superscript t]Bu)₂I₂(THF)₂ (1) and U(NPh)₂I₂(THF)₃ (2) (where [superscript t]Bu is tert-butyl and THF is tetrahydrofuran). Both compounds have been fully characterized by standard analytical techniques, including x-ray crystallography, and the chemical bonding between the metal center and the nitrogen ligands was quantified by using hybrid density functional theory calculations. As expected for a uranyl analog, these complexes exhibit linear N-U-N linkages and very short U-N bonds. In addition, the theoretical calculations show strong involvement of the 5f and 6d electrons in the U-N bonding.
Publisher
American Association for the Advancement of Science,The American Association for the Advancement of Science
Subject
