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Accelerated Discovery in Organic Photocatalysis Using High-Throughput Robotic Platforms
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Accelerated Discovery in Organic Photocatalysis Using High-Throughput Robotic Platforms
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Accelerated Discovery in Organic Photocatalysis Using High-Throughput Robotic Platforms
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Dissertation
Accelerated Discovery in Organic Photocatalysis Using High-Throughput Robotic Platforms
2022
Overview
The resurgence of photocatalysis has propelled the development of a variety of novel synthetic reactions powered by visible light. However, the majority of photocatalysts typically used in these reactions are homogenous dyes or expensive organometallic complexes, which have issues with cost, and recyclability which hinders large-scale applications. The following work first summarizes the recent developments in modern photoredox catalysis, along with some advances in high throughput experiments. This thesis then describes the use of a high-throughput screening strategy to discover a covalent triazine framework, CTF-2, as heterogeneous organic photocatalyst for a variety of reactions, including conjugate addition, metallaphotoredox arylation, metallaphotoredox alkylation, dehydrogenative arylation, and fluorination. Finally, progress towards a fully-autonomous workflow for photochemical reaction optimization using mobile robots is highlighted.
