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Crystal growth, structural, optical, laser damage threshold and nonlinear optical properties of Piperazinium citrate single crystal
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Crystal growth, structural, optical, laser damage threshold and nonlinear optical properties of Piperazinium citrate single crystal
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Crystal growth, structural, optical, laser damage threshold and nonlinear optical properties of Piperazinium citrate single crystal
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Journal Article
Crystal growth, structural, optical, laser damage threshold and nonlinear optical properties of Piperazinium citrate single crystal
2024
Overview
Single crystal of Piperazinium citrate (PC) was grown from aqueous solution by slow evaporation solution growth method. Single crystal X-ray diffraction study (SXRD) reveals that the grown crystal belongs to monoclinic system with the space group Pn. The crystalline nature of PC crystal was analyzed by Powder XRD method. The crystal morphology and growth axis of Piperazinium crystal were investigated. The crystal's various functional band frequencies were confirmed through FTIR and FT-Raman spectroscopy analyses. In order to determine the optical transparency, cutoff wavelength, and band gap energy of PC crystal, a UV–Visible spectral study was carried out. The results indicated that the crystal was transparent throughout the entire visible-NIR spectrum. Sharp emission peaks can be seen in the photoluminescence spectrum, indicating ultraviolet (UV) emission. Laser induced damage threshold study was carried out using Nd:YAG laser at operating frequency of 1064 nm. Third-order nonlinear optical properties such as nonlinear refractive index, nonlinear absorption coefficient, and third-order nonlinear susceptibility of the grown PC crystal were calculated by Z-Scan technique.
