Journal Article

Transport of surface-modified multi-walled carbon nanotubes in saturated porous media

Li, Chengliang, Tan, Miaomiao, Liu, Longfei, Li, Deyun

2021

Overview

Carbon nanotubes (CNTs) are widely used and may pose potential environmental risks to soil and groundwater systems. Therefore, it is important to improve current understanding of the fate and transport of CNTs in porous media. In this study, the transport behavior of multi-walled carbon nanotubes (MWCNTs) with different surface modifications were examined in water-saturated sand columns under different pH (5 and 7) and ionic strength (0.1, 1, and 5 mM) conditions. COOH-MWCNTs have the strongest mobility among the five types of MWCNTs, followed by pristine MWCNTs. NH 2 -MWCNTs, Cu-MWCNTs, and Fe-MWCNTs have the weaker mobility. The transport of five types of MWCNTs decreased with the increase of ionic strength, while increased with the increase of pH value. The results suggested that the transport of MWCNTs can be affected by the electrostatic attraction between the functional groups on the surface of MWCNTs and quartz sand. Moreover, the pH and ionic strength of the solution also played an important role in enhancing the transport of MWCNTs, which have great significance for evaluating the transport and fate of MWCNTs in natural environment.

• Publisher: Springer Berlin Heidelberg,Springer Nature B.V
• Subject: Aquatic Pollution / Atmospheric Protection/Air Quality Control/Air Pollution / Carbon / carbon nanotubes / Columns (structural) / Earth and Environmental Science / Ecotoxicology / electrostatic interactions / Environment / Environmental Chemistry / Environmental Health / Environmental risk / Environmental science / Functional groups / Groundwater / Ionic strength / Mobility / Multi wall carbon nanotubes / Nanotechnology / Nanotubes / Natural environment / pH effects / Porous media / quartz / Research Article / Sand / Transport phenomena / Waste Water Technology / Water Management / Water Pollution Control