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Recycling of PBS and PBS Bio-Composites Containing Organic By-Product Waste
by
Ltayef, Mariem
, Scolaro, Cristina
, Dintcheva, Nadka Tz
, Visco, Annamaria
, Di Liberto, Erika Alessia
, Infurna, Giulia
in
Analysis
/ Breweries
/ Chain branching
/ Chemical properties
/ Composite materials
/ Degradation
/ Extrusion
/ Fourier transforms
/ Investigations
/ Italy
/ Mechanical properties
/ Molecular chains
/ Molecular weight
/ Morphology
/ Organic wastes
/ Polybutylene
/ Polybutylenes
/ Polyphenols
/ Recyclability
/ Recycling
/ Recycling (Waste, etc.)
/ Reprocessing
/ Rheology
/ Succinates
/ Surface roughness
/ Sustainability
/ Temperature
/ Tunisia
/ Viscosity
2025
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Recycling of PBS and PBS Bio-Composites Containing Organic By-Product Waste
by
Ltayef, Mariem
, Scolaro, Cristina
, Dintcheva, Nadka Tz
, Visco, Annamaria
, Di Liberto, Erika Alessia
, Infurna, Giulia
in
Analysis
/ Breweries
/ Chain branching
/ Chemical properties
/ Composite materials
/ Degradation
/ Extrusion
/ Fourier transforms
/ Investigations
/ Italy
/ Mechanical properties
/ Molecular chains
/ Molecular weight
/ Morphology
/ Organic wastes
/ Polybutylene
/ Polybutylenes
/ Polyphenols
/ Recyclability
/ Recycling
/ Recycling (Waste, etc.)
/ Reprocessing
/ Rheology
/ Succinates
/ Surface roughness
/ Sustainability
/ Temperature
/ Tunisia
/ Viscosity
2025
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Recycling of PBS and PBS Bio-Composites Containing Organic By-Product Waste
by
Ltayef, Mariem
, Scolaro, Cristina
, Dintcheva, Nadka Tz
, Visco, Annamaria
, Di Liberto, Erika Alessia
, Infurna, Giulia
in
Analysis
/ Breweries
/ Chain branching
/ Chemical properties
/ Composite materials
/ Degradation
/ Extrusion
/ Fourier transforms
/ Investigations
/ Italy
/ Mechanical properties
/ Molecular chains
/ Molecular weight
/ Morphology
/ Organic wastes
/ Polybutylene
/ Polybutylenes
/ Polyphenols
/ Recyclability
/ Recycling
/ Recycling (Waste, etc.)
/ Reprocessing
/ Rheology
/ Succinates
/ Surface roughness
/ Sustainability
/ Temperature
/ Tunisia
/ Viscosity
2025
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Recycling of PBS and PBS Bio-Composites Containing Organic By-Product Waste
Journal Article
Recycling of PBS and PBS Bio-Composites Containing Organic By-Product Waste
2025
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Overview
The current work is driven by applying circular principles, and it investigated the potential recyclability of polybutylene succinate (PBS) containing brewer’s spent grain filler (BSGF, 30 wt%) in comparison to the recyclability of pure PBS. PBS is much more stable than the PBS/BSGF composite during processing cycles. Typically, thermomechanical degradation induces radical formation and branching of the macromolecular chain in PBS. Furthermore, PBS becomes less hydrophilic (by 53%, reaching 84°, approaching the 90° threshold), and its surface roughness increases by about 38% after five processing cycles. BSGF increases the viscosity of the melt, especially at low frequencies, and stabilizes the melt in the PBS/BSGF, which has lower torque variations during processing compared to pure PBS. Furthermore, BSGF in r-PBS/BSGF increases both hydrophilicity (by about 15%, from 75° to 64°) and surface roughness (by about 17%) after five processing cycles of the solid bio-composite and limits the formation of carboxylic groups during thermomechanical degradation. PBS is recyclable five times because it maintains its properties unchanged during extrusion cycles. At least two reprocessing steps are required for PBS/BSGF to obtain an optimal dispersion of BSGF, which can be re-extruded approximately three times. PBS/BSGF after four and five extrusion steps shows increased rigidity (Et PBS/BSGF > Et PBS) and reduced ductility (εb PBS/BSGF < εbt PBS), which could limit the recyclability of the PBS-based composite.
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