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Prenylated Phenol and Benzofuran Derivatives from Aspergillus terreus EN-539, an Endophytic Fungus Derived from Marine Red Alga Laurencia okamurai
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Prenylated Phenol and Benzofuran Derivatives from Aspergillus terreus EN-539, an Endophytic Fungus Derived from Marine Red Alga Laurencia okamurai
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Journal Article
Prenylated Phenol and Benzofuran Derivatives from Aspergillus terreus EN-539, an Endophytic Fungus Derived from Marine Red Alga Laurencia okamurai
2019
Overview
Three new prenylated phenol derivatives, terreprenphenols A-C (
-3), along with four known related compounds (
-
), were isolated from
EN-539, an endophytic fungus obtained from the marine red alga
. The structures of these compounds were established by extensive analysis of 1D/2D NMR data, mass spectrometric data, and optical rotation (OR). The corresponding relationship between absolute configuration and optical rotation for known compounds anodendroic acid (
) and asperterreusine C (
) was ambiguous in literature, and their absolute configurations were therefore discussed and confirmed for the first time by time-dependent density functional (TDDFT) ECD and OR calculations. Compounds
-
inhibited some common aquatic bacteria with MIC values ranging from 2 to 64 μg/mL.
Publisher
MDPI AG,MDPI
Subject
