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Use of Ionic Liquids for π-Conjugated Polymer Electrochemical Devices
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Use of Ionic Liquids for π-Conjugated Polymer Electrochemical Devices
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Journal Article
Use of Ionic Liquids for π-Conjugated Polymer Electrochemical Devices
2002
Overview
π-Conjugated polymers that are electrochemically cycled in ionic liquids have enhanced lifetimes without failure (up to 1 million cycles) and fast cycle switching speeds (100 ms). We report results for electrochemical mechanical actuators, electrochromic windows, and numeric displays made from three types of π-conjugated polymers: polyaniline, polypyrrole, and polythiophene. Experiments were performed under ambient conditions, yet the polymers showed negligible loss in electroactivity. These performance advantages were obtained by using environmentally stable, room-temperature ionic liquids composed of 1-butyl-3-methyl imidazolium cations together with anions such as tetrafluoroborate or hexafluorophosphate.
Publisher
American Association for the Advancement of Science
