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Enhancement of Oxygen Reduction and Mitigation of Ionomer Dry-Out Using Insoluble Heteropoly Acids in Intermediate Temperature Polymer-Electrolyte Membrane Fuel Cells
by
Aricò, Antonino
, Baglio, Vincenzo
, Saccà, Ada
, Gatto, Irene
, Stassi, Alessandro
in
Acids
/ Alloys
/ Assembly
/ Catalysts
/ Cs0.5H0.5PW12O40
/ Electrodes
/ Electrolytes
/ Fuel cells
/ heteropoly acids
/ Humidity
/ intermediate temperature
/ Ionomers
/ Membranes
/ Morphology
/ oxygen reduction
/ polymer electrolyte membrane fuel cell (PEMFC)
/ Polymers
/ Reduction (electrolytic)
/ Relative humidity
/ Temperature
/ X-rays
2015
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Enhancement of Oxygen Reduction and Mitigation of Ionomer Dry-Out Using Insoluble Heteropoly Acids in Intermediate Temperature Polymer-Electrolyte Membrane Fuel Cells
by
Aricò, Antonino
, Baglio, Vincenzo
, Saccà, Ada
, Gatto, Irene
, Stassi, Alessandro
in
Acids
/ Alloys
/ Assembly
/ Catalysts
/ Cs0.5H0.5PW12O40
/ Electrodes
/ Electrolytes
/ Fuel cells
/ heteropoly acids
/ Humidity
/ intermediate temperature
/ Ionomers
/ Membranes
/ Morphology
/ oxygen reduction
/ polymer electrolyte membrane fuel cell (PEMFC)
/ Polymers
/ Reduction (electrolytic)
/ Relative humidity
/ Temperature
/ X-rays
2015
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Enhancement of Oxygen Reduction and Mitigation of Ionomer Dry-Out Using Insoluble Heteropoly Acids in Intermediate Temperature Polymer-Electrolyte Membrane Fuel Cells
by
Aricò, Antonino
, Baglio, Vincenzo
, Saccà, Ada
, Gatto, Irene
, Stassi, Alessandro
in
Acids
/ Alloys
/ Assembly
/ Catalysts
/ Cs0.5H0.5PW12O40
/ Electrodes
/ Electrolytes
/ Fuel cells
/ heteropoly acids
/ Humidity
/ intermediate temperature
/ Ionomers
/ Membranes
/ Morphology
/ oxygen reduction
/ polymer electrolyte membrane fuel cell (PEMFC)
/ Polymers
/ Reduction (electrolytic)
/ Relative humidity
/ Temperature
/ X-rays
2015
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Enhancement of Oxygen Reduction and Mitigation of Ionomer Dry-Out Using Insoluble Heteropoly Acids in Intermediate Temperature Polymer-Electrolyte Membrane Fuel Cells
Journal Article
Enhancement of Oxygen Reduction and Mitigation of Ionomer Dry-Out Using Insoluble Heteropoly Acids in Intermediate Temperature Polymer-Electrolyte Membrane Fuel Cells
2015
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Overview
The use of Cs0.5H0.5PW12O40 insoluble salt as a superacid promoter in the catalyst layer of a polymer electrolyte membrane fuel cell (PEMFC) has been investigated. An increase of performance has been recorded at intermediate temperatures (110–130 °C) and under low relative humidity (R.H.). The promoter appears to mitigate the ionomer dry-out effects in the catalytic layer and produces an increase of the extent of the catalyst-electrolyte interface as demonstrated by cyclic voltammetry analysis. These effects are also corroborated by a significant decrease of polarization resistance at intermediate temperatures. Such characteristics have been demonstrated for a conventional membrane-electrode assembly based on a Pt-Co alloy and a Nafion 115 membrane.
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