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Colorimetric determination of ferrous ion via morphology transition of gold nanorods
by
Zhang, Xiao
, Yang, Ping
, Lu, Simin
, Chen, Ling
in
Absorption spectra
/ Analytical Chemistry
/ Catalysis
/ Characterization and Evaluation of Materials
/ Chemistry
/ Chemistry and Materials Science
/ Colorimetry
/ Etching
/ Extinction
/ Ferrous ions
/ Gold
/ Hydrogen peroxide
/ Iron
/ Iron compounds
/ Microengineering
/ Morphology
/ Nanochemistry
/ Nanorods
/ Nanotechnology
/ Nitrates
/ Optical properties
/ Original Paper
/ Oxidation
/ Transmission electron microscopy
2018
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Colorimetric determination of ferrous ion via morphology transition of gold nanorods
by
Zhang, Xiao
, Yang, Ping
, Lu, Simin
, Chen, Ling
in
Absorption spectra
/ Analytical Chemistry
/ Catalysis
/ Characterization and Evaluation of Materials
/ Chemistry
/ Chemistry and Materials Science
/ Colorimetry
/ Etching
/ Extinction
/ Ferrous ions
/ Gold
/ Hydrogen peroxide
/ Iron
/ Iron compounds
/ Microengineering
/ Morphology
/ Nanochemistry
/ Nanorods
/ Nanotechnology
/ Nitrates
/ Optical properties
/ Original Paper
/ Oxidation
/ Transmission electron microscopy
2018
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While trying to remove the title from your shelf something went wrong :( Kindly try again later!
Do you wish to request the book?
Colorimetric determination of ferrous ion via morphology transition of gold nanorods
by
Zhang, Xiao
, Yang, Ping
, Lu, Simin
, Chen, Ling
in
Absorption spectra
/ Analytical Chemistry
/ Catalysis
/ Characterization and Evaluation of Materials
/ Chemistry
/ Chemistry and Materials Science
/ Colorimetry
/ Etching
/ Extinction
/ Ferrous ions
/ Gold
/ Hydrogen peroxide
/ Iron
/ Iron compounds
/ Microengineering
/ Morphology
/ Nanochemistry
/ Nanorods
/ Nanotechnology
/ Nitrates
/ Optical properties
/ Original Paper
/ Oxidation
/ Transmission electron microscopy
2018
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Colorimetric determination of ferrous ion via morphology transition of gold nanorods
Journal Article
Colorimetric determination of ferrous ion via morphology transition of gold nanorods
2018
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Overview
A colorimetric method is described for the determination of ferrous ion (Fe
2+
) with high sensitivity and selectivity. The method is based on catalytic etching of gold nanorod (NR). In an acid condition, Fe
2+
reacts with H
2
O
2
to produce superoxide radical (O
2
•−
) that etches gold NRs from the low energy surface along the longitudinal direction preferentially. As a result, the changes in the absorption spectrum and color of gold NR can be measured and also can be detected visually. Under the optimal conditions, the assay has very low detection limit (13.5 nM) and a linear response in a concentration range of 75 to 1 μM. The method was applied to the determination of Fe
2+
in spiked samples of fetal bovine serum and also transferred to a kind of test stripe for use in fast practical applications. A unique colorimetric sensing method is demonstrated for the colorimetric detection of Fe
2+
, again based on the oxidation of gold nanorods which leads to the blue-shift of the absorption.
Graphical abstract
A unique colorimetric sensing method was shown for the colorimetric detection of Fe
2+
. Fe
2+
reacts with H
2
O
2
to generate superoxide radical that oxidize gold nanorods. This leads to a color change from blue-green to pink.
Publisher
Springer Vienna,Springer,Springer Nature B.V
Subject
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