Journal Article

Gram-scale bottom-up flash graphene synthesis

Ren, Muqing, Wang, Zhe, Shahsavari, Rouzbeh, Algozeeb, Wala Ali, Luong, Duy X., Advincula, Paul A., Tour, James M., McHugh, Emily A., Guo, Hua, Stanford, Michael G., Bets, Ksenia V., Kittrell, Carter, Yakobson, Boris I., Salvatierra, Rodrigo V., Bhatt, Mahesh, Chen, Weiyin, Mancevski, Vladimir

2020

Overview

Most bulk-scale graphene is produced by a top-down approach, exfoliating graphite, which often requires large amounts of solvent with high-energy mixing, shearing, sonication or electrochemical treatment 1 – 3 . Although chemical oxidation of graphite to graphene oxide promotes exfoliation, it requires harsh oxidants and leaves the graphene with a defective perforated structure after the subsequent reduction step 3 , 4 . Bottom-up synthesis of high-quality graphene is often restricted to ultrasmall amounts if performed by chemical vapour deposition or advanced synthetic organic methods, or it provides a defect-ridden structure if carried out in bulk solution 4 – 6 . Here we show that flash Joule heating of inexpensive carbon sources—such as coal, petroleum coke, biochar, carbon black, discarded food, rubber tyres and mixed plastic waste—can afford gram-scale quantities of graphene in less than one second. The product, named flash graphene (FG) after the process used to produce it, shows turbostratic arrangement (that is, little order) between the stacked graphene layers. FG synthesis uses no furnace and no solvents or reactive gases. Yields depend on the carbon content of the source; when using a high-carbon source, such as carbon black, anthracitic coal or calcined coke, yields can range from 80 to 90 per cent with carbon purity greater than 99 per cent. No purification steps are necessary. Raman spectroscopy analysis shows a low-intensity or absent D band for FG, indicating that FG has among the lowest defect concentrations reported so far for graphene, and confirms the turbostratic stacking of FG, which is clearly distinguished from turbostratic graphite. The disordered orientation of FG layers facilitates its rapid exfoliation upon mixing during composite formation. The electric energy cost for FG synthesis is only about 7.2 kilojoules per gram, which could render FG suitable for use in bulk composites of plastic, metals, plywood, concrete and other building materials. Flash Joule heating of inexpensive carbon sources is used to produce gram-scale quantities of high-quality graphene in under a second, without the need for a furnace, solvents or reactive gases.

• Publisher: Nature Publishing Group UK,Nature Publishing Group
• Subject: 119/118 / 140/146 / 639/301/357/918/1055 / 639/638/549/2263 / Anthracite / Black carbon / Building materials / Carbon / Carbon black / Carbon content / Carbon sources / Charcoal / Chemical properties / Chemical synthesis / Chemical vapor deposition / Coal / Coffee / Coke / Concrete / Concrete construction / Construction materials / Defects / Electrochemistry / Electrodes / Energy costs / Exfoliation / Gases / Graphene / Graphite / Humanities and Social Sciences / Joule heating / Metals / Methods / multidisciplinary / Ohmic dissipation / Organic chemistry / Oxidants / Oxidation / Oxidizing agents / Petroleum coke / Plastic debris / Plywood / Polyethylene terephthalate / Polymer matrix composites / Purification / Raman spectroscopy / Resistance heating / Rubber / Science / Science (multidisciplinary) / Shearing / Solvents / Sonication / Spectroscopy / Spectrum analysis / Synthesis / Tires