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Designed Mesoporous Architecture by 10–100 nm TiO2 as Electron Transport Materials in Carbon-Based Multiporous-Layered-Electrode Perovskite Solar Cells
by
Shioki, Takaya
, Tsuji, Ryuki
, Ito, Seigo
, Oishi, Kota
, Fukumuro, Naoki
in
Carbon
/ Carbon black
/ carbon electrode
/ Cellulose
/ Chemical industry
/ Crystals
/ Efficiency
/ electrode transport layer
/ Electrodes
/ Electron transport
/ Energy conversion efficiency
/ Ethanol
/ Field emission microscopy
/ Glass substrates
/ Graphite
/ Humidity
/ Morphology
/ Nanoparticles
/ Particle size
/ perovskite solar cell
/ Perovskites
/ Photoabsorption
/ Photovoltaic cells
/ Photovoltaics
/ Porosity
/ Porous materials
/ Scanning electron microscopy
/ Screen printing
/ Short circuit currents
/ Short-circuit current
/ Size distribution
/ Solar cells
/ Spectroscopy
/ TiO2
/ Titanium
/ Titanium dioxide
/ X-ray diffraction
2024
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Designed Mesoporous Architecture by 10–100 nm TiO2 as Electron Transport Materials in Carbon-Based Multiporous-Layered-Electrode Perovskite Solar Cells
by
Shioki, Takaya
, Tsuji, Ryuki
, Ito, Seigo
, Oishi, Kota
, Fukumuro, Naoki
in
Carbon
/ Carbon black
/ carbon electrode
/ Cellulose
/ Chemical industry
/ Crystals
/ Efficiency
/ electrode transport layer
/ Electrodes
/ Electron transport
/ Energy conversion efficiency
/ Ethanol
/ Field emission microscopy
/ Glass substrates
/ Graphite
/ Humidity
/ Morphology
/ Nanoparticles
/ Particle size
/ perovskite solar cell
/ Perovskites
/ Photoabsorption
/ Photovoltaic cells
/ Photovoltaics
/ Porosity
/ Porous materials
/ Scanning electron microscopy
/ Screen printing
/ Short circuit currents
/ Short-circuit current
/ Size distribution
/ Solar cells
/ Spectroscopy
/ TiO2
/ Titanium
/ Titanium dioxide
/ X-ray diffraction
2024
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Designed Mesoporous Architecture by 10–100 nm TiO2 as Electron Transport Materials in Carbon-Based Multiporous-Layered-Electrode Perovskite Solar Cells
by
Shioki, Takaya
, Tsuji, Ryuki
, Ito, Seigo
, Oishi, Kota
, Fukumuro, Naoki
in
Carbon
/ Carbon black
/ carbon electrode
/ Cellulose
/ Chemical industry
/ Crystals
/ Efficiency
/ electrode transport layer
/ Electrodes
/ Electron transport
/ Energy conversion efficiency
/ Ethanol
/ Field emission microscopy
/ Glass substrates
/ Graphite
/ Humidity
/ Morphology
/ Nanoparticles
/ Particle size
/ perovskite solar cell
/ Perovskites
/ Photoabsorption
/ Photovoltaic cells
/ Photovoltaics
/ Porosity
/ Porous materials
/ Scanning electron microscopy
/ Screen printing
/ Short circuit currents
/ Short-circuit current
/ Size distribution
/ Solar cells
/ Spectroscopy
/ TiO2
/ Titanium
/ Titanium dioxide
/ X-ray diffraction
2024
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Designed Mesoporous Architecture by 10–100 nm TiO2 as Electron Transport Materials in Carbon-Based Multiporous-Layered-Electrode Perovskite Solar Cells
Journal Article
Designed Mesoporous Architecture by 10–100 nm TiO2 as Electron Transport Materials in Carbon-Based Multiporous-Layered-Electrode Perovskite Solar Cells
2024
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Overview
Fully printable carbon-based multiporous-layered-electrode perovskite solar cells (MPLE-PSCs) are easy to fabricate and have excellent durability. In this study, the porosity of the mesoporous TiO2 layer as the electron transport layer in MPLE-PSCs was controlled by varying the particle diameter of TiO2 nanoparticles from 14 nm to 98 nm. Furthermore, the results of absorbed photon-to-current conversion efficiency, visible light reflectance spectroscopy, pore-size distribution, X-ray diffraction, field emission scanning electron microscopy, and photovoltaic parameters of MPLE-PSCs are discussed. Although the porous TiO2 layer with smaller nanoparticles showed higher photoabsorption, it was found that the more voids of perovskite crystals created in the TiO2 porous layer, the smaller the particle size (<18 nm). The porous TiO2 layers with particles over 26 nm are well filled with perovskite crystals, resulting in a higher photovoltaic capacity with TiO2 particles over 26 nm. As a result, the short-circuit current density (JSC) showed a maximum value using 43 nm TiO2 particles, with an average power conversion efficiency (PCE) of 10.56 ± 1.42%. Moreover, the PCE showed a maximum value of 12.20% by using 26 nm TiO2 nanoparticles.
Publisher
MDPI AG
Subject
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